Gas phase polymerization of butadiene—kinetics, particle size distribution, modeling
作者： Knut Zoellner , Karl-Heinz Reichert
DOI: 10.1016/S0009-2509(01)00080-X
关键词:
摘要: The gas phase polymerization of butadiene with a heterogeneous Ziegler catalyst based on neodymium was studied by using videomicroscopy and stirred tank reactor laboratory scale. By the start up particle growth individual particles measured at different reaction conditions. In reactor, kinetics size distribution polymer formed studied. For modeling performance, single model uniform site implemented in environment model. A dynamic population balance is used to simulate change during polymerization. solved simultaneously include influence diffusion limitation experimental results simulation show good agreement.
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