Reactions of [HOs 3 (CO) 8 {µ 3 -Ph 2 PCH(R)P(Ph)C 6 H 4 }] (R = H, Me) with Bu 3 SnH: synthesis and structure of bimetallic Os-Sn clusters
作者： Md Tuhinur R Joy , Md Miaz Uddin , Nikhil C Bhoumik , Shishir Ghosh , Shariff E Kabir
DOI: 10.1007/S11243-020-00431-7
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摘要: Reactions of unsaturated [HOs3(CO)8{µ3-Ph2PCH(R)P(Ph)C6H4}] (R = H, Me) with Bu3SnH are examined. reacts at room temperature to afford [H2Os3(CO)8(SnBu3){µ3-Ph2PCH(R)P(Ph)C6H4}] (1) via oxidative addition the Sn‒H bond parent cluster. Heating 1 in refluxing toluene leads formation [H2Os3(CO)7(SnBu3){µ3-Ph2PCH(R)P(Ph)C6H4}] (2) through decarbonylation. Cluster 2 exists two isomeric forms solution which has been probed by VT NMR spectroscopy. The new Os-Sn bimetallic clusters have characterized a combination analytical and spectroscopic data together single-crystal X-ray diffraction analysis.
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sci-hub.st 参考文章(59)
Mohd Rezaul Haque, Md Jakir Hossain, Ahibur Rahaman, Shishir Ghosh, Shariff E Kabir, Graeme Hogarth, Derek A Tocher, None, Oxidative-addition of germanium–hydrogen bonds to triosmium centers: Reactions of Os 3 (CO) 10 (μ-dppm) and Os 3 (CO) 8 (μ 3 -Ph 2 PCH 2 P(Ph)C 6 H 4 )(μ-H) with Ph 3 GeH Journal of Organometallic Chemistry. ,vol. 812, pp. 240- 246 ,(2016) , 10.1016/J.JORGANCHEM.2015.05.060
R.D. Cortright, J.A. Dumesic, Microcalorimetric, Spectroscopic, and Kinetic Studies of Silica Supported Pt and Pt/Sn Catalysts for Isobutane Dehydrogenation Journal of Catalysis. ,vol. 148, pp. 771- 778 ,(1994) , 10.1006/JCAT.1994.1263
Richard D. Adams, Burjor Captain, Jack L. Smith, Michael B. Hall, Chad L. Beddie, Charles Edwin Webster, Superloading of tin ligands into rhodium and iridium carbonyl cluster complexes. Inorganic Chemistry. ,vol. 43, pp. 7576- 7578 ,(2004) , 10.1021/IC0489589
Shishir Ghosh, Graeme Hogarth, Shariff E Kabir, Arun K Raha, Michael G Richmond, Jagodish C Sarker, None, Backbone Modified Small Bite-Angle Diphosphines: Synthesis, Structure and Regioselective Thermal Rearrangements of Os3(CO)10{μ-Ph2PCH(Me)PPh2} Journal of Cluster Science. ,vol. 23, pp. 781- 798 ,(2012) , 10.1007/S10876-012-0471-1
Richard D. Adams, Burjor Captain, Lei Zhu, A New Tris(diphenylstannylene)triosmium Carbonyl Cluster Complex and Its Reactions with Pt(PBut3)2 and Pt(PPh3)4 Organometallics. ,vol. 25, pp. 2049- 2054 ,(2006) , 10.1021/OM060002D
John Meurig Thomas, Richard D. Adams, Erin M. Boswell, Burjor Captain, Henrik Grönbeck, Robert Raja, Synthesis, characterization, electronic structure and catalytic performance of bimetallic and trimetallic nanoparticles containing tin. Faraday Discussions. ,vol. 138, pp. 301- 315 ,(2008) , 10.1039/B706151J
Florence Epron, Christelle Carnevillier, Patrice Marécot, Catalytic properties in n-heptane reforming of Pt–Sn and Pt–Ir–Sn/Al2O3 catalysts prepared by surface redox reaction Applied Catalysis A-general. ,vol. 295, pp. 157- 169 ,(2005) , 10.1016/J.APCATA.2005.08.006
Richard D. Adams, Yuwei Kan, Vitaly Rassolov, Qiang Zhang, Tetraruthenium carbonyl complexes containing germyl and stannyl ligands from the reactions of Ru4(CO)13(μ-H)2 with HGePh3 and HSnPh3 Journal of Organometallic Chemistry. ,vol. 730, pp. 20- 31 ,(2013) , 10.1016/J.JORGANCHEM.2012.08.021
Javier A. Cabeza, R. Jesus Franco, Angela Llamazares, Victor Riera, Claudette Bois, Yves Jeannin, Reactivity of tertiary silanes and stannanes with an edge-bridged triruthenium carbonyl cluster complex Inorganic Chemistry. ,vol. 32, pp. 4640- 4642 ,(1993) , 10.1021/IC00073A028
T. Fujikawa, F.H. Ribeiro, G.A. Somorjai, The Effect of Sn on the Reactions of n-Hexane and Cyclohexane over Polycrystalline Pt Foils Journal of Catalysis. ,vol. 178, pp. 58- 65 ,(1998) , 10.1006/JCAT.1998.2118