Scope and limitations of the irreversible thermodynamics and the solution diffusion models for the separation of binary and multi-component systems in reverse osmosis process

作者: M.A. Al-Obaidi , C. Kara-Zaitri , I.M. Mujtaba

DOI: 10.1016/J.COMPCHEMENG.2017.02.001

关键词:

摘要: Abstract Reverse osmosis process is used in many industrial applications ranging from solute-solvent to solvent–solvent and gaseous separation. A number of theoretical models have been developed describe the separation fluxes solvent solute such processes. This paper looks into scope limitations two main (the irreversible thermodynamics solution diffusion models) past by several researchers for feed Despite investigation other complex models, simple concepts these accelerate feasibility implementation reverse different types systems variety industries. Briefly, an extensive review mathematical conducted collecting more than 70 examples literature this study. In addition, has covered improvement make them compatible with multi-component consideration concentration polarization solvent-solute-membrane interaction.

参考文章(69)
James Ingram Marriott, Detailed modelling and optimal design of membrane separation systems Doctoral thesis, University of London.. ,(2001)
ARMIN KARGOL, A Description of Reverse Osmosis using Practical Kedem-Katchalsky Equations. Journal of Biological Physics. ,vol. 23, pp. 111- 120 ,(1997) , 10.1023/A:1004928519666
Ramamurti Rangarajan, Takeshi Matsuura, E. C. Goodhue, S. Sourirajan, Free Energy Parameters for Reverse Osmosis Separation of Some Inorganic Ions and Ion Pairs in Aqueous Solutions Industrial & Engineering Chemistry Process Design and Development. ,vol. 15, pp. 529- 534 ,(1976) , 10.1021/I260060A009
J.G. Wijmans, R.W. Baker, The solution-diffusion model: a review Journal of Membrane Science. ,vol. 107, pp. 1- 21 ,(1995) , 10.1016/0376-7388(95)00102-I
E.A. Mason, H.K. Lonsdale, Statistical-mechanical theory of membrane transport Journal of Membrane Science. ,vol. 51, pp. 1- 81 ,(1990) , 10.1016/S0376-7388(00)80894-7
Takashi Fukuda, Wongkang Yang, Akira Yamauchi, KCl transport mechanism across charged mosaic membrane in KCl-sucrose mixed system Journal of Membrane Science. ,vol. 212, pp. 255- 261 ,(2003) , 10.1016/S0376-7388(02)00506-9