On the coordination behaviour of NO3- in coordination compounds with Ag+ : Part 1. Solubility effect on the formation of coordination polymer networks between AgNO3 and L(L= ethanediyl bis(isonicotinate) as a function of solvent
作者： Adeline Y. Robin , Jorge L. Sagu? , Katharina M. Fromm
DOI: 10.1039/B517191A
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摘要: The influence of the solubility AgNO3 in three solvent systems is studied for reaction between and ligand L (= ethanediyl bis(isonicotinate)). Three solid state structures are obtained, differing relative ratio Ag : L first case, polymorphism second. Ag–O(NO3−) distance correlates strongly with used solvent. Solution studies prove indeed existence close ion contact pairs less good solvents, where as solvation observed solvents AgNO3. different compared to two solvated which H2O demonstrates coordination nitrate anion via H-bonding.
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