Thermodynamic and experimental approach of electrochemical reduction of CO2 in molten carbonates
作者： D. Chery , V. Albin , V. Lair , M. Cassir
DOI: 10.1016/J.IJHYDENE.2014.03.113
关键词:
摘要: … The key point, even before selecting the best electrocatalytic electrode, is the choice of the molten carbonate electrolyte composition, temperature and oxoacidity level, which will allow …
sci-hub.se 参考文章(27)
douglas Inman, B. Trémillon, Reactions in solution : an applied analytical approach John Wiley & Sons. ,(1997)
ZhenLan Li, Hary Devianto, Sung Pil Yoon, Jonghee Han, Tae-Hoon Lim, Ho-In Lee, Electrolyte effect on the catalytic performance of Ni-based catalysts for direct internal reforming molten carbonate fuel cell International Journal of Hydrogen Energy. ,vol. 35, pp. 13041- 13047 ,(2010) , 10.1016/J.IJHYDENE.2010.04.058
P. Claes, B. Thirion, J. Glibert, Solubility of CO2 in the molten NA2CO3-K2CO3 (42 mol %) eutectic mixture at 800°C Electrochimica Acta. ,vol. 41, pp. 141- 146 ,(1996) , 10.1016/0013-4686(95)00278-M
M. Cassir, S.J. McPhail, A. Moreno, Strategies and new developments in the field of molten carbonates and high-temperature fuel cells in the carbon cycle International Journal of Hydrogen Energy. ,vol. 37, pp. 19345- 19350 ,(2012) , 10.1016/J.IJHYDENE.2011.11.006
Dae Sung Park, Zhenlan Li, Hary Devianto, Ho-In Lee, Characteristics of alkali-resistant Ni/MgAl2O4 catalyst for direct internal reforming molten carbonate fuel cell International Journal of Hydrogen Energy. ,vol. 35, pp. 5673- 5680 ,(2010) , 10.1016/J.IJHYDENE.2010.03.043
G. Moutiers, M. Cassir, J. Devynck, Oxygen reduced species in molten Li2CO3 + K2CO3 (42.7 + 57.3 mol%) at 650°C: A thermodynamic, voltammetric and convolution potential sweep characterization Journal of Electroanalytical Chemistry. ,vol. 324, pp. 175- 189 ,(1992) , 10.1016/0022-0728(92)80044-5
V. Lair, V. Albin, A. Ringuedé, M. Cassir, Theoretical predictions vs. experimental measurements of the electrical conductivity of molten Li2CO3–K2CO3 modified by additives International Journal of Hydrogen Energy. ,vol. 37, pp. 19357- 19364 ,(2012) , 10.1016/J.IJHYDENE.2011.09.153
Gilles Moutiers, Michel Cassir, Colette Piolet, Jacques Devynck, Thermodynamic and voltammetric study of oxygen systems in molten Na2CO3K2CO3 (56-44 mol.%) eutectic at 750°C Electrochimica Acta. ,vol. 36, pp. 1063- 1071 ,(1991) , 10.1016/0013-4686(91)85316-Y
C. Yuh, R. Johnsen, M. Farooque, H. Maru, Status of carbonate fuel cell materials Journal of Power Sources. ,vol. 56, pp. 1- 10 ,(1995) , 10.1016/0378-7753(95)80001-W
V. Chauvaut, M. Cassir, Y. Denos, Behavior of titanium species in molten Li2CO3–Na2CO3 and Li2CO3–K2CO3 under anodic and cathodic conditions. I – Thermodynamic predictions at 550–750°C Electrochimica Acta. ,vol. 43, pp. 1991- 2003 ,(1998) , 10.1016/S0013-4686(97)10139-6