Prediction of vapor pressure and density for nonaqueous solutions of the ionic liquid 1-ethyl-3-methylimidazolium ethyl sulfate using PC-SAFT equation of state

作者: Hemayat Shekaari , Mohammed Taghi Zafarani-Moattar , Saeid Faraji , Masumeh Mokhtarpour

DOI: 10.1016/J.FLUID.2019.112320

关键词:

摘要: Abstract The experimental data on density and vapor pressure for nonaqueous solution of ionic liquids are important not only the design optimization chemical processes, but also from theoretical perspective to predict physical properties modeling under different conditions. In this study, solutions liquid, 1-ethyl-3-methylimidazolium ethyl sulfate [EMIM][ES] in some polar organic solvents, i.e. 1-propanol, ethanol methanol, dilute region liquid concentration were measured by use isopiestic method at 298.15 K. regard, Perturbed Chain Statistical Association Fluid equation state (PC-SAFT) is used prediction investigated systems. obtained results PC-SAFT provide reliable accurate predictions with absolute average deviations (AAD), 0.01 0.084 , respectively.

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