The influence of different donor/acceptor matches on chromophore's nonlinear optical activity
作者： Huajun Xu , Haoran Wang , Chaolei Hu , Mingkai Fu , Yanling He
DOI: 10.1016/J.DYEPIG.2016.04.023
关键词:
摘要: Abstracts In this work, a series of novel second order nonlinear optical chromophores modified by heteroatom-groups in electron-donor has been synthesized and systematically investigated. The resulting exhibited both good thermal stability solubility common organic solvents. UV–Vis spectra density functional theory calculations were carried out to investigate the influence on electro-optic activities. results revealed that increasing strength will not always improve activity chromophore. There is best match for acceptor. As activities, doped polymer film- d3 displayed highest coefficient value 37 pm/v at doping concentration 25 wt%. These indicated activities could be enhanced finding acceptor chromophore design.
sci-hub.se 参考文章(51)
Jialei Liu, Wu Gao, I.V. Kityk, Xinhou Liu, Zhen Zhen, Optimization of polycyclic electron-donors based on julolidinyl structure in push–pull chromophores for second order NLO effects Dyes and Pigments. ,vol. 122, pp. 74- 84 ,(2015) , 10.1016/J.DYEPIG.2015.06.007
Yuhui Yang, Shuhui Bo, Haoran Wang, Fenggang Liu, Jialei Liu, Ling Qiu, Zhen Zhen, Xinhou Liu, Novel chromophores with excellent electro-optic activity based on double-donor chromophores by optimizing thiophene bridges Dyes and Pigments. ,vol. 122, pp. 139- 146 ,(2015) , 10.1016/J.DYEPIG.2015.06.012
Fenggang Liu, Yuhui Yang, Haoran Wang, Jialei Liu, Chaolei Hu, Fuyang Huo, Shuhui Bo, Zhen Zhen, Xinhou Liu, Ling Qiu, Comparative studies on structure–nonlinearity relationships in a series of novel second-order nonlinear optical chromophores with different aromatic amine donors Dyes and Pigments. ,vol. 120, pp. 347- 356 ,(2015) , 10.1016/J.DYEPIG.2015.05.003
Huajun Xu, Dan Yang, Fenggang Liu, Mingkai Fu, Shuhui Bo, Xinhou Liu, Yuan Cao, Nonlinear optical chromophores based on Dewar's rules: enhancement of electro-optic activity by introducing heteroatoms into the donor or bridge. Physical Chemistry Chemical Physics. ,vol. 17, pp. 29679- 29688 ,(2015) , 10.1039/C5CP04959H
Yi Liao, Bruce E. Eichinger, Kimberly A. Firestone, Marnie Haller, Jingdong Luo, Werner Kaminsky, Jason B. Benedict, Philip J. Reid, Alex K-Y Jen, Larry R. Dalton, Bruce H. Robinson, Systematic study of the structure-property relationship of a series of ferrocenyl nonlinear optical chromophores. Journal of the American Chemical Society. ,vol. 127, pp. 2758- 2766 ,(2005) , 10.1021/JA0449123
Mingqian He, Thomas M. Leslie, John A. Sinicropi, Sean M. Garner, Leon D. Reed, Synthesis of Chromophores with Extremely High Electro-optic Activities. 2. Isophorone- and Combined Isophorone−Thiophene-Based Chromophores Chemistry of Materials. ,vol. 14, pp. 4669- 4675 ,(2002) , 10.1021/CM0204066
Larry R. Dalton, Philip A. Sullivan, Denise H. Bale, Electric field poled organic electro-optic materials: state of the art and future prospects. Chemical Reviews. ,vol. 110, pp. 25- 55 ,(2010) , 10.1021/CR9000429
David R. Kanis, Mark A. Ratner, Tobin J. Marks, Design and construction of molecular assemblies with large second-order optical nonlinearities. Quantum chemical aspects Chemical Reviews. ,vol. 94, pp. 195- 242 ,(1994) , 10.1021/CR00025A007
Jingdong Luo, Marnie Haller, Hong Ma, Sen Liu, Tae-Dong Kim, Yanqing Tian, Baoquan Chen, Sei-Hum Jang, Larry R. Dalton, Alex K.-Y. Jen, Nanoscale architectural control and macromolecular engineering of nonlinear optical dendrimers and polymers for electro-optics Journal of Physical Chemistry B. ,vol. 108, pp. 8523- 8530 ,(2004) , 10.1021/JP036714O
Ross M. Dickson, Axel D. Becke, Basis‐set‐free local density‐functional calculations of geometries of polyatomic molecules Journal of Chemical Physics. ,vol. 99, pp. 3898- 3905 ,(1993) , 10.1063/1.466134