Process for the trimerization of diisocyanates

作者: Josef Disteldorf , Werner Hubel , Elmar Wolf

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摘要: In a process for the trimerization of diisocyanates in presence catalyst comprising quaternary ammonium salts organic acids having formula: ##STR1## wherein X represents same or different radicals selected from group consisting C 1 -C 20 alkyl, 3 8 cycloalkyl, and 2 aralkyl; two taken together with at least one other heteroatom forming hetero-ring three nitrogen atoms through common hetero-atom such that said heterocyclic ring structure is triethylene diamine, methyl quinuclidine, N-methylmorpholine, N-ethylmorpholine, N,N'-dimethylpiperazine; R cycloalkyl aralkyl, R" hydrogen; R+R" form 12 alkyl radical; R' hydrogen, hydroxyl radical, optionally containing CH.sub.(3-b) Z b group, b=1 to OH, improvement comprising: reacting diisocyanate an amount 0.02 0.1% by weight calculated on compound be trimerized temperature ranging 40° 120° C.

参考文章(2)
Dewey G. Holland, Felix P. Carroll, Ibrahim S. Bechara, Rocco L. Mascioli, Catalysis of organic isocyanate reactions ,(1975)
Heinz Uelzmann, Edwin M. Maxey, Hubert J. Fabris, Trimerization of aromatic isocyanates catalyzed by certain ammonium salts ,(1975)