Infrared spectroscopy of double-four-ring silicates

作者: E.J.J. Groenen , C.A. Emeis , J.P. van den Berg , P.C. de Jong-Versloot

DOI: 10.1016/0144-2449(87)90018-2

关键词:

摘要: Abstract Attenuated—total—reflection infrared spectroscopy has been applied to characterize tetramethylammonium double-four-ring silicates in solution as well hydrate crystals. It is shown that silicate solutions at elevated temperatures (up 85°C) still contain significant concentrations of anions. Furthermore, the temperature-dependent shift equilibrium between anions appears be fully reversible. A relation role zeolite syntheses suggested.

参考文章(7)
Adrian Nikolaevich Lazarev, Vibrational Spectra and Structure of Silicates ,(2013)
D. Hoebbel, G. Garz�, G. Engelhardt, A. Vargha, Über die Konstitution und Verteilung der Silicatanionen in wäßrigen Tetramethylammonium‐Silicatlösungen Zeitschrift für anorganische und allgemeine Chemie. ,vol. 494, pp. 31- 42 ,(1982) , 10.1002/ZAAC.19824940104
Neil H. Ray, Richard J. Plaisted, The constitution of aqueous silicate solutions Journal of The Chemical Society-dalton Transactions. pp. 475- 481 ,(1983) , 10.1039/DT9830000475
Gosse Boxhoorn, Olof Sudmeijer, Piet H. G. van Kasteren, Identification of a double five-ring silicate, a possible precursor in the synthesis of ZSM-5 Journal of the Chemical Society, Chemical Communications. pp. 1416- 1418 ,(1983) , 10.1039/C39830001416
Günter Engelhardt, Dagobert Hoebbel, Zur Temperaturabhängigkeit der Silicatanionenverteilung in wäßrigen Tetraalkylammonium-silicatlösungen Zeitschrift für Chemie. ,vol. 23, pp. 33- 34 ,(2010) , 10.1002/ZFCH.19830230120
P. K. Dutta, D. C. Shieh, Raman spectroscopic studies of aqueous tetramethylammonium silicate solutions Journal of Raman Spectroscopy. ,vol. 16, pp. 312- 314 ,(1985) , 10.1002/JRS.1250160505