Spray-Dried Iron Fischer−Tropsch Catalysts. 1. Effect of Structure on the Attrition Resistance of the Catalysts in the Calcined State
作者： Rong Zhao , James G. Goodwin, , K. Jothimurugesan , Santosh K. Gangwal , James J. Spivey
DOI: 10.1021/IE000644F
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摘要: The use of Fe Fischer−Tropsch (F−T) catalysts in slurry bubble column reactors (SBCRs) has been problematic the past because their poor attrition resistance. Recently, we have reported preparation spray-dried F−T having resistance suitable for SBCR use, but reason this improvement was not clear. This paper focuses on research done to better understand high some prepared. Understanding relationship between catalyst and composition/structure is important attrition-resistant catalysts. In present study, two series composition Fe/Cu/K/SiO2 with different amounts precipitated and/or binder SiO2 were investigated. All studied evaluated calcined form. minimize any possible due phase change (such as can occur during activation syn...
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