A new tetranuclear defective dicubane azide-bridged cobalt(II) complex

作者: Joan Cano , Franz A. Mautner , Christian Berger , Roland C. Fischer , Ramon Vicente

DOI: 10.1016/J.POLY.2012.11.007

关键词:

摘要: Abstract The new tetranuclear cobalt(II) complex with formula [Co4(N3)8(4,5-diazafluoren-9-one)4] (1) is reported. Complex 1 a defective dicubane azide-bridged compound showing only azido bridging ligands in the μ1,1– and μ1,1,1– coordination modes. magnetic properties of are Magnetic susceptibility measurements indicate ferromagnetic coupling. data have been fitted to 2 K by considering two different superexchange coupling constants. out-of-phase signal χM″ displays frequency-dependence below approximately 9 K.

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