Variations in the Charge and Open-Circuit Potential of a Platinum Electrode during Adsorption of Iodine and Iodide Ions
作者： B. I. Podlovchenko
关键词:
摘要: The adsorption of iodine and iodide anions on a Pt/Pt electrode (0.5 M H2SO4 as supporting solution) is compared using potentiodynamic galvanostatic charging curves, transients the current open-circuit potential (OCP), analytical measurements. Variations in charge OCP during obey relationships derived for strong neutral species ions hydrogen with formation irreversibly adsorbed atoms. main product I2 I– chemisorption acid solutions However, occurs noticeable amounts above monolayer form that undergo electrodesorption cathodic polarization to potentials beginning adsorption. In presence atoms, zero total oxygen region.
springer.com
sci-hub.se 参考文章(20)
Gaston Charlot, Méthodes de la chimie analytique : analyse quantitative minérale Masson et Cie. ,(1961)
Michael J. Weaver, Potentials of Zero Charge for Platinum(111)−Aqueous Interfaces: A Combined Assessment from In-Situ and Ultrahigh-Vacuum Measurements Langmuir. ,vol. 14, pp. 3932- 3936 ,(1998) , 10.1021/LA9801054
J. H. White, Hector D. Abruna, Electrosorption of iodide on platinum(111) studied in situ by x-ray absorption spectroscopy The Journal of Physical Chemistry. ,vol. 92, pp. 7131- 7134 ,(1988) , 10.1021/J100336A019
Andrzej Czerwiński, The adsorption of carbon oxides on a palladium electrode from acidic solution Journal of Electroanalytical Chemistry. ,vol. 379, pp. 487- 493 ,(1994) , 10.1016/0022-0728(94)87173-6
R.W. Evans, D. Godfrey, B. Cowie, G.A. Attard, Surface-EXAFS of irreversibly adsorbed iodine on Pt{111} and Pt{100} Journal of Electroanalytical Chemistry. ,vol. 340, pp. 365- 371 ,(1992) , 10.1016/0022-0728(92)80312-R
S. Cradock, R. A. Whiteford, Photoelectron spectra of the methyl, silyl and germyl derivatives of the group VI elements Journal of the Chemical Society, Faraday Transactions. ,vol. 68, pp. 281- 288 ,(1972) , 10.1039/F29726800281
D Zurawski, L Rice, M Hourani, A Wieckowski, None, The in-situ preparation of well-defined, single crystal electrodes Journal of Electroanalytical Chemistry. ,vol. 230, pp. 221- 231 ,(1987) , 10.1016/0022-0728(87)80144-4
J. Clavilier, J.M. Orts, R. Gómez, J.M. Feliu, A. Aldaz, Comparison of electrosorption at activated polycrystalline and Pt(531) kinked platinum electrodes: surface voltammetry and charge displacement on potentiostatic CO adsorption Journal of Electroanalytical Chemistry. ,vol. 404, pp. 281- 289 ,(1996) , 10.1016/0022-0728(95)04365-9
Andrzej Wieckowski, Stephen D. Rosasco, Bruce C. Schardt, John L. Stickney, Arthur T. Hubbard, Preparation of well-defined surfaces at atmospheric pressure: studies by electrochemistry and LEED of platinum(100) pretreated with iodine Inorganic Chemistry. ,vol. 23, pp. 565- 569 ,(1984) , 10.1021/IC00173A016
Thomas E. Felter, Arthur T. Hubbard, L.e.e.d. and electrochemistry of iodine on Pt(100) and Pt(111) single-crystal surfaces Journal of Electroanalytical Chemistry. ,vol. 100, pp. 473- 491 ,(1979) , 10.1016/S0022-0728(79)80179-5