Equilibria Involving the CF(g) and CF2(g) Radicals at High Temperatures
作者： John L. Margrave , Karl Wieland
DOI: 10.1063/1.1699296
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摘要: The absorption spectrum of carbon tetrafluoride (CF4) gas thermally decomposed under equilibrium conditions in a graphite tube furnace shows the bands CF2 at temperature T≈1900°K and also CF T≈2400°K. These results are approximate agreement with thermodynamic calculations made by Potocki Mann when high value 170 kcal/mole for heat sublimation f values about 10−3 both assumed.
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