Mg–M–LiH alloys prepared by mechanical milling and their hydrogen storage characteristics

作者: K. Suárez-Alcántara , A.F. Palacios-Lazcano , T. Funatsu , J.G. Cabañas-Moreno

DOI: 10.1016/J.IJHYDENE.2015.04.083

关键词:

摘要: Abstract Mg 96 M 2 (LiH) (M = Y, Zn, Al, Ag), 98 and 4 powder alloys were produced by ball milling deliberately air-exposed 12 h in order to investigate their hydrogen storage properties. The addition of LiH at the level 2 mol% had a beneficial effect on kinetics hydriding dehydriding processes 300 350 °C compared mechanically milled powders. However, additions Ag, Zn Y had an opposite hydriding/dehydriding kinetics. Al provided small advantage capacity among tested materials. effects air-exposure analyzed, it was demonstrated that set Mg-alloys heavily oxidized is still viable.

参考文章(39)
H Shao, M Felderhoff, F Schüth, C Weidenthaler, Nanostructured Ti-catalyzed MgH2 for hydrogen storage Nanotechnology. ,vol. 22, pp. 235401- 235408 ,(2011) , 10.1088/0957-4484/22/23/235401
H. Smithson, C. A. Marianetti, D. Morgan, A. Van der Ven, A. Predith, G. Ceder, First-principles study of the stability and electronic structure of metal hydrides Physical Review B. ,vol. 66, pp. 144107- ,(2002) , 10.1103/PHYSREVB.66.144107
H Yukawa, T Matsumura, M Morinaga, Chemical bond state and hydride stability of hydrogen storage alloys Journal of Alloys and Compounds. ,vol. 293, pp. 227- 230 ,(1999) , 10.1016/S0925-8388(99)00424-7
W. Grochala, P.P. Edwards, Chemical tuning of the thermal decomposition temperature of inorganic hydrides : Computational aspects Journal of Alloys and Compounds. ,vol. 404, pp. 31- 34 ,(2005) , 10.1016/J.JALLCOM.2005.01.135
J Huot, S Bouaricha, S Boily, J.-P Dodelet, D Guay, R Schulz, Increase of specific surface area of metal hydrides by lixiviation Journal of Alloys and Compounds. ,vol. 266, pp. 307- 310 ,(1998) , 10.1016/S0925-8388(97)00440-4
J. Huot, G. Liang, R. Schulz, Mechanically alloyed metal hydride systems Applied Physics A. ,vol. 72, pp. 187- 195 ,(2001) , 10.1007/S003390100772
O. Gutfleisch, S. Dal Toè, M. Herrich, A. Handstein, A. Pratt, Hydrogen sorption properties of Mg-1 wt.% Ni-0.2 wt.% Pd prepared by reactive milling Journal of Alloys and Compounds. ,vol. 404, pp. 413- 416 ,(2005) , 10.1016/J.JALLCOM.2004.09.083
Gagik Barkhordarian, Thomas Klassen, Rüdiger Bormann, Fast hydrogen sorption kinetics of nanocrystalline Mg using Nb2O5 as catalyst Scripta Materialia. ,vol. 49, pp. 213- 217 ,(2003) , 10.1016/S1359-6462(03)00259-8
Kyle C. Smith, Timothy S. Fisher, Umesh V. Waghmare, Ricardo Grau-Crespo, Dopant-vacancy binding effects in Li-doped magnesium hydride Physical Review B. ,vol. 82, pp. 134109- ,(2010) , 10.1103/PHYSREVB.82.134109
K H J Buschow, P C P Bouten, A R Miedema, Hydrides formed from intermetallic compounds of two transition metals: a special class of ternary alloys Reports on Progress in Physics. ,vol. 45, pp. 937- 1039 ,(1982) , 10.1088/0034-4885/45/9/001