Porous single-crystal NaTi2(PO4)3 via liquid transformation of TiO2 nanosheets for flexible aqueous Na-ion capacitor

作者: Qi Yang , Sihan Cui , Yifei Ge , Zijie Tang , Zhuoxin Liu

DOI: 10.1016/J.NANOEN.2018.06.017

关键词:

摘要: Abstract Aqueous Na-ion capacitor and battery are of great significance for both wearable electronics stationary energy storage due to the inherent safety low cost. However, conventional NaTi2(PO4)3 materials with irregular morphology large size prepared by solid-state reaction still hinder application these systems. Herein, a newly structured porous single-crystal uniform sizes was fabricated via well-designed novel liquid transformation ultrathin TiO2 nanosheets, followed coating conductive carbon sheath. To best our knowledge, this is first report structure materials. Examined in three-electrode cell, electrode demonstrates an outstanding rate capability 80–102 mA h g−1 at varied current densities 0.5–3 A g−1 synergistic effect between nanostructure stability originated from structure. The high-quality also assembled N-doped fabricate aqueous robust flexibility. This work paves way designing advanced Na super ion conductor (NASICON) based

参考文章(42)
Xianyong Wu, Yuliang Cao, Xinping Ai, Jiangfeng Qian, Hanxi Yang, A low-cost and environmentally benign aqueous rechargeable sodium-ion battery based on NaTi2(PO4)3–Na2NiFe(CN)6 intercalation chemistry Electrochemistry Communications. ,vol. 31, pp. 145- 148 ,(2013) , 10.1016/J.ELECOM.2013.03.013
Xianhong Rui, Wenping Sun, Chao Wu, Yan Yu, Qingyu Yan, An Advanced Sodium‐Ion Battery Composed of Carbon Coated Na3V2(PO4)3 in a Porous Graphene Network Advanced Materials. ,vol. 27, pp. 6670- 6676 ,(2015) , 10.1002/ADMA.201502864
Jie Yang, Hua Wang, Pengfei Hu, Juanjuan Qi, Lin Guo, Lihua Wang, A High‐Rate and Ultralong‐Life Sodium‐Ion Battery Based on NaTi2(PO4)3 Nanocubes with Synergistic Coating of Carbon and Rutile TiO2 Small. ,vol. 11, pp. 3744- 3749 ,(2015) , 10.1002/SMLL.201500144
Zhibin Yang, Jue Deng, Xuli Chen, Jing Ren, Huisheng Peng, A Highly Stretchable, Fiber‐Shaped Supercapacitor Angewandte Chemie. ,vol. 52, pp. 13453- 13457 ,(2013) , 10.1002/ANIE.201307619
Liumin Suo, Oleg Borodin, Tao Gao, Marco Olguin, Janet Ho, Xiulin Fan, Chao Luo, Chunsheng Wang, Kang Xu, "Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries. Science. ,vol. 350, pp. 938- 943 ,(2015) , 10.1126/SCIENCE.AAB1595
Haegyeom Kim, Jihyun Hong, Kyu-Young Park, Hyungsub Kim, Sung-Wook Kim, Kisuk Kang, Aqueous Rechargeable Li and Na Ion Batteries Chemical Reviews. ,vol. 114, pp. 11788- 11827 ,(2014) , 10.1021/CR500232Y
Minshen Zhu, Yang Huang, Yan Huang, Zengxia Pei, Qi Xue, Hongfei Li, Huiyuan Geng, Chunyi Zhi, Capacitance Enhancement in a Semiconductor Nanostructure‐Based Supercapacitor by Solar Light and a Self‐Powered Supercapacitor–Photodetector System Advanced Functional Materials. ,vol. 26, pp. 4481- 4490 ,(2016) , 10.1002/ADFM.201601260
Yan Huang, Minshen Zhu, Yang Huang, Zengxia Pei, Hongfei Li, Zifeng Wang, Qi Xue, Chunyi Zhi, Multifunctional Energy Storage and Conversion Devices Advanced Materials. ,vol. 28, pp. 8344- 8364 ,(2016) , 10.1002/ADMA.201601928