A direct route to angularly substituted hydrindanes. Formal synthesis of bakkenolide-A and synthesis of an advanced intermediate to umbellactal
作者： Soumitra Maity , Subrata Ghosh
DOI: 10.1016/J.TET.2009.09.029
关键词:
摘要: A direct route for the synthesis of highly functionalized angularly substituted hydrindanes has been developed. The key step involves RO-RCM an appropriately norbornene derivative. hydrindane derivative obtained in this way used to accomplish a formal bakkenolide-A. This protocol also extended advanced intermediate diterpene umbellactal.
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