作者: Emmanuel Auer , Andreas Freund , Peter Panster , Gernot Stein , Thomas Tacke
DOI: 10.1016/S0167-2991(97)80908-1
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摘要: Mono- and bimetallic Rh catalysts were evaluated for the stereoselective reductive amination of alkylphenols to corresponding alkylcyclohexylamines. Rhodium as well catalyst formulations with platinum found be most suitable this one-step hydrogenation. Both chemo-and stereoselectivity that reaction depend on amount base added other parameters such kind solvent and/or support.