Influence of membrane filtration on extraction and characteristics of lignin from a kraft dissolving pulp mill pre-hydrolysate

作者: Adil Mazar , Naceur Jemaa , Waleed Wafa Al Dajani , Mariya Marinova , Michel Perrier

DOI: 10.1016/J.INDCROP.2018.08.046

关键词:

摘要: Abstract During dissolving pulp production, the extraction of hemicellulose and other organics from hardwood chips prior to kraft pulping process can be performed using steam or hot water. The pre-hydrolysate this step is rich in sugars contains a considerable amount lignin. It estimated that lignin content stream as high 28 t d−1 for mill producing about 550 t d−1 pulp. In article, we report on recovery its characterization. use membrane filtration system has been experimentally validated an effective method concentrating extracting Three membranes with different molecular weight cut-offs (100, 10 1 kDa) have tested. subsequent step, sulfuric acid was added concentrated precipitate recovered characterized respect purity, distribution chemical properties. Approximately 99% retention both achieved 1 kDa membrane, 44.4% total being extracted by precipitation method. found low (2810 Da), homogeneity (Mw/Mn = 1.15), purity (91%). These characteristics make very attractive candidate niche applications.

参考文章(25)
Aikfei Ang, Zaidon Ashaari, Edi Suhaimi Bakar, Nor Azowa Ibrahim, Characterisation of Sequential Solvent Fractionation and Base-catalysed Depolymerisation of Treated Alkali Lignin Bioresources. ,vol. 10, pp. 4137- 4151 ,(2015) , 10.15376/BIORES.10.3.4137-4151
Qiang Wang, M. Sarwar Jahan, Shanshan Liu, Qingxian Miao, Yonghao Ni, Lignin removal enhancement from prehydrolysis liquor of kraft-based dissolving pulp production by laccase-induced polymerization Bioresource Technology. ,vol. 164, pp. 380- 385 ,(2014) , 10.1016/J.BIORTECH.2014.05.005
Olumoye Ajao, Mohamed Rahni, Mariya Marinova, Hassan Chadjaa, Oumarou Savadogo, Retention and flux characteristics of nanofiltration membranes during hemicellulose prehydrolysate concentration Chemical Engineering Journal. ,vol. 260, pp. 605- 615 ,(2015) , 10.1016/J.CEJ.2014.09.007
Zhaojiang Wang, Jungang Jiang, Xiaojun Wang, Yingjuan Fu, Zongquan Li, Fengshan Zhang, Menghua Qin, Selective removal of phenolic lignin derivatives enables sugars recovery from wood prehydrolysis liquor with remarkable yield Bioresource Technology. ,vol. 174, pp. 198- 203 ,(2014) , 10.1016/J.BIORTECH.2014.10.025
J. W. T. Merewether, Lignin XIV. The Precipitation of Lignin from Kraft Black Liquor Holzforschung. ,vol. 15, pp. 168- 177 ,(1961) , 10.1515/HFSG.1961.15.6.168
Haiqiang Shi, Pedram Fatehi, Huining Xiao, Yonghao Ni, A process for isolating lignin of pre-hydrolysis liquor of kraft pulping process based on surfactant and calcium oxide treatments Biochemical Engineering Journal. ,vol. 68, pp. 19- 24 ,(2012) , 10.1016/J.BEJ.2012.06.017
M. P. Pandey, C. S. Kim, Lignin Depolymerization and Conversion: A Review of Thermochemical Methods Chemical Engineering & Technology. ,vol. 34, pp. 29- 41 ,(2011) , 10.1002/CEAT.201000270
Qiang Wang, Shanshan Liu, Guihua Yang, Jiachuan Chen, Modeling laccase-induced lignin removal in prehydrolysis liquor from kraft-based dissolving pulp production. Bioresource Technology. ,vol. 175, pp. 638- 641 ,(2015) , 10.1016/J.BIORTECH.2014.10.149
R. Beauchet, F. Monteil-Rivera, J.M. Lavoie, Conversion of lignin to aromatic-based chemicals (L-chems) and biofuels (L-fuels). Bioresource Technology. ,vol. 121, pp. 328- 334 ,(2012) , 10.1016/J.BIORTECH.2012.06.061