Zinc complexes of pyridyl-tetrazole derivatives – Highly fluorescent materials

作者: Ursula Sheridan , John F. Gallagher , Aggelos Philippidis , John McGinley

DOI: 10.1016/J.ICA.2015.03.024

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摘要: Abstract The ligands L1Et and L2Et were synthesised hydrolysed in situ to form carboxylates, utilising methods previously established, for the purpose of investigating ability carboxylate functionalised pyridyl tetrazoles coordination polymers. These then reacted with ZnCl2 displayed interesting chemistry as position alkylation site appeared have some effect on sphere metal centre. Solid state fluorescence spectroscopy was carried out Zn(II) compounds their corresponding free acid at room temperature. crystal structure also solved showed co-planarity two rings.

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