Use of additives in porphyrin-tape/C60 near-infrared photodetectors
作者： Jeramy D. Zimmerman , Eric K. Yu , Vyacheslav V. Diev , Kenneth Hanson , Mark E. Thompson
DOI: 10.1016/J.ORGEL.2011.02.013
关键词:
摘要: Abstract We demonstrate organic heterojunction photodetectors sensitive to wavelengths λ > 1500 nm based on a solution processed Zn–porphyrin-dimer donor layer that includes phenyl-C61-butyric acid methyl ester (PCBM) and/or 4,4′-bipyridyl (Bipy) additives, and an evaporated C60 acceptor layer. The inclusion of PCBM results in up 20-fold increase differential resistance, while the Bipy 100% external quantum efficiency (EQE) compared devices lacking additives. have peak specific detectivities D∗ = 8.8 ± 0.2 × 1011 Jones (EQE = 3.6 ± 0.1%) at λ = 1130 nm, D∗ = 8.2 ± 0.2 × 1010 (EQE = 10.5 ± 0.2%) λ = 1400 nm. maximum λ = 1400 nm is 13.5 ± 0.3%, approximately double previously reported near infrared detectors.
elsevier.com
sci-hub.se 参考文章(23)
Karl M. Kadish, Kevin M. Smith, Roger Guilard, The porphyrin handbook Academic Press. ,(2002)
Irina Beletskaya, Vladimir S. Tyurin, Aslan Yu. Tsivadze, Roger Guilard, Christine Stern, Supramolecular chemistry of metalloporphyrins. Chemical Reviews. ,vol. 109, pp. 1659- 1713 ,(2009) , 10.1021/CR800247A
Guodan Wei, Siyi Wang, Kyle Renshaw, Mark E. Thompson, Stephen R. Forrest, Solution-processed squaraine bulk heterojunction photovoltaic cells. ACS Nano. ,vol. 4, pp. 1927- 1934 ,(2010) , 10.1021/NN100195J
Martin Gouterman, Study of the Effects of Substitution on the Absorption Spectra of Porphin The Journal of Chemical Physics. ,vol. 30, pp. 1139- 1161 ,(1959) , 10.1063/1.1730148
Peter D. W. Boyd, Michael C. Hodgson, Clifton E. F. Rickard, Allen G. Oliver, Leila Chaker, Penelope J. Brothers, Robert D. Bolskar, Fook S. Tham, Christopher A. Reed, SELECTIVE SUPRAMOLECULAR PORPHYRIN/FULLERENE INTERACTIONS Journal of the American Chemical Society. ,vol. 121, pp. 10487- 10495 ,(1999) , 10.1021/JA992165H
Akihiko Tsuda, Atsuhiro Osuka, Fully conjugated porphyrin tapes with electronic absorption bands that reach into infrared. Science. ,vol. 293, pp. 79- 82 ,(2001) , 10.1126/SCIENCE.1059552
Martin Gouterman, Spectra of porphyrins Journal of Molecular Spectroscopy. ,vol. 6, pp. 138- 163 ,(1961) , 10.1016/0022-2852(61)90236-3
Charles Michael Drain, Alessandro Varotto, Ivana Radivojevic, Self-Organized Porphyrinic Materials Chemical Reviews. ,vol. 109, pp. 1630- 1658 ,(2009) , 10.1021/CR8002483
N. C. Giebink, G. P. Wiederrecht, M. R. Wasielewski, S. R. Forrest, Ideal diode equation for organic heterojunctions. I. Derivation and application Physical Review B. ,vol. 82, pp. 155305- ,(2010) , 10.1103/PHYSREVB.82.155305
Li Wen, Benjamin C. Duck, Paul C. Dastoor, Seth C. Rasmussen, Poly(2,3-dihexylthieno[3,4-b]pyrazine) via GRIM Polymerization: Simple Preparation of a Solution Processable, Low-Band-Gap Conjugated Polymer Macromolecules. ,vol. 41, pp. 4576- 4578 ,(2008) , 10.1021/MA801057S