Carbon Dioxide Reduction to Methylamines under Metal-Free Conditions†
作者： Enguerrand Blondiaux , Jacky Pouessel , Thibault Cantat
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摘要: The first metal-free catalysts are reported for the methylation of amines with carbon dioxide. Proazaphosphatrane superbases prove to be highly active in reductive functionalization CO2, presence hydroboranes. new methodology enables NH bonds a wide variety amines, including secondary increased chemoselectivity.
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