Alkynylcarbene Complexes of Transition Metals as Suitable Substrates for Stereoselective Cycloadditions
作者： L. Jordi , A. Llebaria , S. Ricart , J. M. Viñas , J. M. Moreto
DOI: 10.1007/978-94-011-1666-4_11
关键词:
摘要: Strong electronic effects of the carbene-metal unit on adjacent functionalities in alkynylcarbene metal (Cr,W) complexes may be regarded as main cause for easy and stereocontrolled cycloadditions with a variety substrates.
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sci-hub.st 参考文章(9)
Ernst Otto Fischer, Hans Jürgen Kalder, Übergangsmetall—carben-komplexe : C. Aminolyse einer carben-alkoxygruppe und addition an eine dreifachbindung als konkurrenzreaktion — umsetzung von phenylacetylenyl(äthoxy)carbenpentacarbonyl-chrom und-wolfram mit dimethylamin Journal of Organometallic Chemistry. ,vol. 131, pp. 57- 64 ,(1977) , 10.1016/S0022-328X(00)91358-5
Roald Hoffmann, The Conservation of Orbital Symmetry Angewandte Chemie International Edition in English. ,vol. 8, pp. 781- 853 ,(1969) , 10.1002/ANIE.196907811
Barry B. Snider, David M. Roush, David J. Rodini, Domingo Gonzalez, David Spindell, Lewis acid catalyzed reactions of acetylenic esters with alkenes. Stereochemistry and regiochemistry The Journal of Organic Chemistry. ,vol. 45, pp. 2773- 2785 ,(1980) , 10.1021/JO01302A007
Katherine L. Faron, William D. Wulff, The chromium and tungsten pentacarbonyl groups as reactivity auxiliaries in [2 + 2] cycloadditions Journal of the American Chemical Society. ,vol. 110, pp. 8727- 8729 ,(1988) , 10.1021/JA00234A042
Katherine L. Faron, William D. Wulff, Ene versus [2 + 2] cycloaddition reactions of Fischer carbene complexes: an unusual effect of silicon on the product partition and the stereospecificity Journal of the American Chemical Society. ,vol. 112, pp. 6419- 6420 ,(1990) , 10.1021/JA00173A052
Rolf Pipoh, Rudi Van Eldik, Siu Ling B. Wang, William D. Wulff, Pressure acceleration of [2 + 2] cycloaddition reactions on the coordinated ligand of chromium and tungsten pentacarbonyl carbene complexes Organometallics. ,vol. 11, pp. 490- 492 ,(1992) , 10.1021/OM00037A085
Francisco Camps, Amadeu Llebaria, Joseph M Moretó, Susagna Ricart, Josep M Viñas, Joseph Ros, Ramón Yáñez, None, Conjugate addition of alcohols to alkynylalkoxycarbene metal (Cr, W) complexes Journal of Organometallic Chemistry. ,vol. 401, ,(1991) , 10.1016/0022-328X(91)86215-C
Francisco Camps, Josep M. Moretó, Susagna Ricart, Josep M. Viñas, Fischer Carbene Complexes Facilitate the Intramolecular Pauson-Khand Reaction Angewandte Chemie International Edition in English. ,vol. 30, pp. 1470- 1472 ,(1991) , 10.1002/ANIE.199114701
Barry B. Snider, David J. Rodini, Robin S. E. Conn, Stuart Sealfon, Lewis acid catalyzed reactions of methyl propiolate with unactivated alkenes Journal of the American Chemical Society. ,vol. 101, pp. 5283- 5293 ,(1979) , 10.1021/JA00512A029