Lewis-saure metallkomplexe
作者： Klaus Raab , Bernhard Olgemöller , Klaus Schloter , Wolfgang Beck
DOI: 10.1016/S0022-328X(00)85959-8
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摘要: Abstract (OC) 5 ReFBF 3 (I) is obtained by abstraction of H - or CH from ReH ReCH , respectively, using Ph CBF 4 . Treatment I with water vapour yields the trifluorohydroxoborato complex ReOHBF (III). The reaction σ and π-donors L proceeds to give salts [(OC) ReL] + BF (L (CH ) 2 CO, CN, C propene, pentene-1) under mild conditions. ReC ] Na [Re(OC) form ethylene bridged Re(OC)
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