Probability distribution of enantiomorphous forms in spontaneous generation of optically active substances.
作者： R. E. Pincock , R. R. Perkins , A. S. Ma , K. R. Wilson
DOI: 10.1126/SCIENCE.174.4013.1018
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摘要: The crystallization of 1, l9—binaphthyl from its racemic melt is an example spontaneous generation optical activity. distribution specific rotations in 200 individual samples varied [α]D = —218 degrees to +206 with a mean +0.14 degree and standard deviation 86.4 degrees. This resolution into enantiomers determined by chance development, equal probability, right- or left-handed crystallites; it can be controlled made stereospecific addition dissymmetric compounds at low concentrations.
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E. Havinga, Spontaneous formation of optically active substances. Biochimica et Biophysica Acta. ,vol. 13, pp. 171- 174 ,(1954) , 10.1016/0006-3002(54)90300-5
T. L. V. Ulbricht, Asymmetry: the non-conservation of parity and optical activity Quarterly Reviews, Chemical Society. ,vol. 13, pp. 48- 60 ,(1959) , 10.1039/QR9591300048
A. S. GARAY, ORIGIN AND ROLE OF OPTICAL ISOMERY IN LIFE. Nature. ,vol. 219, pp. 338- 340 ,(1968) , 10.1038/219338A0
Robert M. Secor, Resolution of Optical Isomers by Crystallization Procedures. Chemical Reviews. ,vol. 63, pp. 297- 309 ,(1963) , 10.1021/CR60223A006
George Wald, THE ORIGIN OF OPTICAL ACTIVITY Annals of the New York Academy of Sciences. ,vol. 69, pp. 352- 368 ,(1957) , 10.1111/J.1749-6632.1957.TB49671.X
Henri Kagan, A. Moradpour, J. F. Nicoud, Gilbert Balavoine, G. Tsoucaris, Photochemistry with circularly polarized light. Synthesis of optically active hexahelicene Journal of the American Chemical Society. ,vol. 93, pp. 2353- 2354 ,(1971) , 10.1021/JA00738A061
Kaoru Harada, Origin and development of optical activity of organic compounds on the primordial Earth Naturwissenschaften. ,vol. 57, pp. 114- 119 ,(1970) , 10.1007/BF00600045
Yukio Yamagata, A hypothesis for the asymmetric appearance of biomolecules on earth Journal of Theoretical Biology. ,vol. 11, pp. 495- 498 ,(1966) , 10.1016/0022-5193(66)90110-X
Richard E. Pincock, Keith R. Wilson, Solid state resolution of racemic 1,1'-binaphthyl Journal of the American Chemical Society. ,vol. 93, pp. 1291- 1292 ,(1971) , 10.1021/JA00734A058