Fluorine-containing organozinc reagents: II. The crystal structure of (1, 1-dichloro-2, 2, 2-trifluoroethylzinc chloride) · 2(dimethylformamide)
作者： Daniel Bellusˇ , Bernd Klingert , Robert W. Lang , Grety Rihs
DOI: 10.1016/0022-328X(88)80520-5
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摘要: Abstract The DMF complex of 1, 1-dichloro-2, 2, 2-trifluoroethylzinc chloride, a key intermediate in the one pot synthesis CF 3 CCl 2 -substituted alcohols, has been isolated and its structure determined by 13 C NMR spectroscopy X-ray diffraction. This is first structural study perhalogenated alkylzinc halide results show to be monomeric.
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