Magnetic and electrical properties of Co1−xCuxRh2S4
作者： F.K. Lotgering
DOI: 10.1016/0022-3697(69)90206-6
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摘要: Abstract Samples of Co 1− x Cu r Rh 2 S 4 with 0.1 ≦ 1 show a practically temperature-independent resistivity 10 −2 −10 −3 Ω cm and positive Seebeck coefficient decreasing from 125 μV/deg for = to ≈25μV/deg 0.5 1. The material is antiferromagnetic 0 ≈0.7 paramagnetic strongest spontaneous magnetization occurs at moment ≈0.8 μ B /molecule found. conduction attributed holes in the valence band. occurrence small saturation composition range 0.4 0.7 explained tentatively double exchange between 2+ 3+ on tetrahedral sites.
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G. Haacke, L. C. Beegle, Electrical Transport in FeCr2S4‐CuCr2S4 Spinels Journal of Applied Physics. ,vol. 39, pp. 656- 657 ,(1968) , 10.1063/1.2163563
G. Blasse, Antiferromagnetism of CoRh2S4 Physics Letters. ,vol. 19, pp. 110- 110 ,(1965) , 10.1016/0031-9163(65)90735-3
R. R. Heikes, T. R. McGuire, R. J. Happel, Role of Double Exchange in the Magnetic Structure of Li x Mn 1-x Se Physical Review. ,vol. 121, pp. 703- 707 ,(1961) , 10.1103/PHYSREV.121.703
F. K. Lotgering, R. P. van Stapele, Magnetic Properties and Electrical Conduction of Copper‐Containing Sulfo‐ and Selenospinels Journal of Applied Physics. ,vol. 39, pp. 417- 423 ,(1968) , 10.1063/1.2163459
G. Blasse, D.J. Schipper, Sulphospinels containing rhodium Journal of Inorganic and Nuclear Chemistry. ,vol. 26, pp. 1467- 1468 ,(1964) , 10.1016/0022-1902(64)80136-6
R. P. van Stapele, H. G. Beljers, P. F. Bongers, H. Zijlstra, Ground State of Divalent Co Ions in Cs3CoCl5 and Cs3CoBr5 The Journal of Chemical Physics. ,vol. 44, pp. 3719- 3725 ,(1966) , 10.1063/1.1726525
F. S. Ham, G. W. Ludwig, G. D. Watkins, H. H. Woodbury, Spin Hamiltonian of Co 2 Physical Review Letters. ,vol. 5, pp. 468- 470 ,(1960) , 10.1103/PHYSREVLETT.5.468
F.K. Lotgering, R.P. Van Stapele, G.H.A.M. Van Der Steen, J.S. Van Wieringen, Magnetic properties, conductivity and ionic ordering in Fe1−xCuxCr2S4 Journal of Physics and Chemistry of Solids. ,vol. 30, pp. 799- 804 ,(1969) , 10.1016/0022-3697(69)90274-1
P. -G. de Gennes, Effects of Double Exchange in Magnetic Crystals Physical Review. ,vol. 118, pp. 141- 154 ,(1960) , 10.1103/PHYSREV.118.141
F.K. Lotgering, Mixed crystals between binary sulphides or selenides with spinel structure Journal of Physics and Chemistry of Solids. ,vol. 29, pp. 699- 709 ,(1967) , 10.1016/0022-3697(68)90038-3