Copper(II) tetrazolato complexes: Role in oxidation catalysis and protein binding
作者： Manideepa Saha , Komal M Vyas , Luísa MDRS Martins , Nuno MR Martins , Armando JL Pombeiro
DOI: 10.1016/J.POLY.2017.04.016
关键词:
摘要: Abstract Three new coordination complexes [Cu 2 (phen) (ptz) 4 ] ( 1 ), [Cu(phen)(pmtz) ) and [Cu(phen)(pytz) 3 (ptz = 5-phenyltetrazolate, pmtz = 5-(2-pyrimidyl)tetrazolate pytz = 5-(2-pyridyl)tetrazolate) have been synthesized using metal mediated [2+3] cycloaddition reaction between copper bound azide polymer different organonitriles. All structurally characterized by elemental analysis, IR spectroscopy single-crystal X-ray diffraction. Complex shows a dinuclear structure via bridging ptz, while reveal mononuclear structures. These were explored as homogeneous catalysts for the selective peroxidative (with tBuOOH) oxidation of cyclohexane to cyclohexanol cyclohexanone (KA oil) under very mild green (solvent- additive-free) conditions microwave irradiation. The catecholase-like activity Cu(II) was investigated employing 3,5-di- tert -butylcatechol (DTBC) convenient model substrate, which showed first order kinetics with respect substrate in -butyl catechol benzoquinone (DTBQ). Further, interaction Cu(II)-tetrazolato bovine serum albumin (BSA) studied experimentally well through molecular docking obtain detailed binding information BSA, revealed higher complex than .
core.ac.uk 
sci-hub.se 参考文章(69)
Fayezeh Samari, Bahram Hemmateenejad, Mojtaba Shamsipur, Mehdi Rashidi, Hamidreza Samouei, Affinity of Two Novel Five-Coordinated Anticancer Pt(II) Complexes to Human and Bovine Serum Albumins: A Spectroscopic Approach Inorganic Chemistry. ,vol. 51, pp. 3454- 3464 ,(2012) , 10.1021/IC202141G
Luísa MDRS Martins, Armando JL Pombeiro, None, Water-Soluble C-Scorpionate Complexes – Catalytic and Biological Applications European Journal of Inorganic Chemistry. ,vol. 2016, pp. 2236- 2252 ,(2016) , 10.1002/EJIC.201600053
Soumen Mistri, Horst Puschmann, Subal Chandra Manna, DNA/protein binding, cytotoxicity and catecholase activity studies of a piperazinyl moiety ligand based nickel(II) complex Polyhedron. ,vol. 115, pp. 155- 163 ,(2016) , 10.1016/J.POLY.2016.05.003
Mathiyan Muralisankar, Surendran Sujith, Nattamai S.P. Bhuvanesh, Anandaram Sreekanth, Synthesis and crystal structure of new monometallic and bimetallic copper(II) complexes with N-substituted isatin thiosemicarbazone ligands: Effects of the complexes on DNA/protein-binding property, DNA cleavage study and in vitro anticancer activity Polyhedron. ,vol. 118, pp. 103- 117 ,(2016) , 10.1016/J.POLY.2016.06.017
Diana Dragancea, Natalia Talmaci, Sergiu Shova, Ghenadie Novitchi, Denisa Darvasiová, Peter Rapta, Martin Breza, Mathea Sophia Galanski, Jozef Kožı́šek, Nuno MR Martins, Luísa MDRS Martins, Armando JL Pombeiro, Vladimir B Arion, None, Vanadium(V) Complexes with Substituted 1,5-bis(2-hydroxybenzaldehyde)carbohydrazones and Their Use As Catalyst Precursors in Oxidation of Cyclohexane Inorganic Chemistry. ,vol. 55, pp. 9187- 9203 ,(2016) , 10.1021/ACS.INORGCHEM.6B01011
Manideepa Saha, Novina Malviya, Mriganka Das, Indrani Choudhuri, Shaikh M. Mobin, Biswarup Pathak, Suman Mukhopadhyay, Effect on catecholase activity and interaction with biomolecules of metal complexes containing differently tuned 5-substituted ancillary tetrazolato ligands Polyhedron. ,vol. 121, pp. 155- 171 ,(2017) , 10.1016/J.POLY.2016.09.035
Ricardo Valdes, Donato Aranda, Heiddy Alvarez, Octavio Antunes, Microwave-Promoted Ring Opening Reaction of Azalactones Letters in Organic Chemistry. ,vol. 4, pp. 35- 38 ,(2007) , 10.2174/157017807780037360
Licun Li, Zonghui Jiang, Daizheng Liao, Shiping Yan, Genglin Wang, Qihua Zhao, Alternating ferromagnetic and antiferromagnetic interactions in the azido-bridged copper(II) chain compound [Cu(phen)(N3)2] n Transition Metal Chemistry. ,vol. 25, pp. 630- 634 ,(2000) , 10.1023/A:1007080714810
Kang Zheng, Ling Zhu, Yan-Tuan Li, Zhi-Yong Wu, Cui-Wei Yan, Synthesis and crystal structure of new dicopper(II) complexes having asymmetric N,N′-bis(substituted)oxamides with DNA/protein binding ability: In vitro anticancer activity and molecular docking studies Journal of Photochemistry and Photobiology B: Biology. ,vol. 149, pp. 129- 142 ,(2015) , 10.1016/J.JPHOTOBIOL.2015.05.014
Isabel W. C. E. Arends, Ulf Hanefeld, Roger Arthur Sheldon, Green Chemistry and Catalysis ,(2007)