Synthesis of Monometallic Ru/TiO 2 Catalysts and Selective Hydrogenation of CO 2 to Formic Acid in Ionic Liquid
作者： Praveenkumar Upadhyay , Vivek Srivastava
DOI: 10.1007/S10562-015-1654-9
关键词:
摘要: We successfully synthesized user friendly, stable, agglomeration free monometallic Ru/Ti-x catalyst for ionic liquid mediated CO2 hydrogenation reaction. Two well defined methods (impregnation and deposition–precipitation) were used to prepare 2 wt% Ru/Ti 1–10 catalysts. Advance analytical techniques applied the characterization of catalytic systems. A series functionalized liquids as a reaction medium not only but also absorbent solubilize gas anchor formic acid (hydrogenation product). Such advance application system offered in more optimized way achieve maximum selectivity (high TON/TOF value acid) with added advantage eight times recycling.
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B. N. Prasanna Kumar, K. N. Mohana, L. Mallesha, Synthesis of N-[{5-Aryl-1,3,4-oxadiazole-2-yl}methyl]-4-methoxyaniline Derivatives and Their Anticonvulsant Activity Journal of Chemistry. ,vol. 2013, pp. 1- 7 ,(2013) , 10.1155/2013/121029
Rajni Ratti, Ionic Liquids: Synthesis and Applications in Catalysis Advances in Chemistry. ,vol. 2014, pp. 1- 16 ,(2014) , 10.1155/2014/729842
Jia Zhao, Lei Ma, Xiao-Liang Xu, Feng Feng, Xiao-Nian Li, Synthesis of carbon-supported Pd/SnO2 catalyst for highly selective hydrogenation of 2,4-difluoronitrobenzene Chinese Chemical Letters. ,vol. 25, pp. 1137- 1140 ,(2014) , 10.1016/J.CCLET.2014.01.024
Fabrizio Nerozzi, Heterogeneous Catalytic Hydrogenation Platinum Metals Review. ,vol. 56, pp. 236- 241 ,(2012) , 10.1595/147106712X654187
Byung Hyo Kim, Michael J. Hackett, Jongnam Park, Taeghwan Hyeon, Synthesis, Characterization, and Application of Ultrasmall Nanoparticles Chemistry of Materials. ,vol. 26, pp. 59- 71 ,(2014) , 10.1021/CM402225Z
Jackson D. Scholten, Bárbara Caroline Leal, Jairton Dupont, Transition Metal Nanoparticle Catalysis in Ionic Liquids ACS Catalysis. ,vol. 2, pp. 184- 200 ,(2012) , 10.1021/CS200525E
Bruce Clapham, Thomas S. Reger, Kim D. Janda, Polymer-supported catalysis in synthetic organic chemistry Tetrahedron. ,vol. 57, pp. 4637- 4662 ,(2001) , 10.1016/S0040-4020(01)00298-8
Juan M. Campelo, Diego Luna, Rafael Luque, José M. Marinas, Antonio A. Romero, Sustainable Preparation of Supported Metal Nanoparticles and Their Applications in Catalysis Chemsuschem. ,vol. 2, pp. 18- 45 ,(2009) , 10.1002/CSSC.200800227
Yoshio Ono, Solid base catalysts for the synthesis of fine chemicals Journal of Catalysis. ,vol. 216, pp. 406- 415 ,(2003) , 10.1016/S0021-9517(02)00120-3
VickyV Mody, Rodney Siwale, Ajay Singh, HardikR Mody, Introduction to metallic nanoparticles Journal of Pharmacy and Bioallied Sciences. ,vol. 2, pp. 282- 289 ,(2010) , 10.4103/0975-7406.72127