Synthesis and crystal structure of bis(malonato)tetra (aqua)barium(II)cobalt(II): [BaCo(C3H2O4)2(H2O)4]

作者: Assia Djeghri , Fadila Balegroune , Achoura Guehria-Laidoudi , Loic Toupet

DOI: 10.1007/S10870-005-3245-X

关键词:

摘要: The title compound [BaCo(C3H2O4)2(H2O)4] was synthesized and its crystal structure determined. is orthorhombic, space group Pccn with a = 18.974(3) A, b 6.783(2) c 9.394(4) A. polymeric consists of edge-sharing BaO8 polyhedra CoO6 octahedra linked together by the malonate groups. geometry around Ba(II) centres slightly distorted square-antiprism Ba–O distances ranging from 2.789(4) to 2.843(4) Around Co(II) centres, coordination forms octahedron Co–O bonds between 2.040(3) 2.238(4)

参考文章(37)
M.N. Burnett, C.K. Johnson, ORTEP-III: Oak Ridge Thermal Ellipsoid Plot Program for crystal structure illustrations Other Information: PBD: Jul 1996. ,(1996) , 10.2172/369685
Catalina Ruiz-Pérez*, Marı́a Hernández-Molina, Joaquı́n Sanchiz, Trinidad López, Francesc Lloret, Miguel Julve*, Synthesis, crystal structure and magnetic properties of the three-dimensional compound [Na2Ni(mal)2(H2O)6]n (H2mal=malonic acid) Inorganica Chimica Acta. ,vol. 298, pp. 245- 250 ,(2000) , 10.1016/S0020-1693(99)00438-7
Yue-Qing Zheng, Jian-Li Lin, Jie Sun, New Suberato-bridged Supramolecular Layers: Crystal Structure of [Cu2(phen)2(C8H12O4)2] · 3 H2O with phen = 1,10-phenanthroline Zeitschrift für anorganische und allgemeine Chemie. ,vol. 627, pp. 1993- 1996 ,(2001) , 10.1002/1521-3749(200108)627:8<1993::AID-ZAAC1993>3.0.CO;2-A
Byoung-Jae Bae, Joon T Park, Il-Hwan Suh, Synthesis and characterization of monomeric Ba and Sr complexes with malonate and Lewis base ligands Journal of Organometallic Chemistry. ,vol. 648, pp. 214- 219 ,(2002) , 10.1016/S0022-328X(01)01412-7
Tapas Kumar Maji, Saugata Sain, Golam Mostafa, Tian-Huey Lu, Joan Ribas, Montserrat Monfort, Nirmalendu Ray Chaudhuri, Magneto−Structural Correlations in 2D and 3D Extended Structures of Manganese(II)−Malonate Systems Inorganic Chemistry. ,vol. 42, pp. 709- 716 ,(2003) , 10.1021/IC020238J
T. Lis, J. Matuszewski, Manganese(II) malonate dihydrate: a reinvestigation Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. ,vol. 35, pp. 2212- 2214 ,(1979) , 10.1107/S0567740879008839
I. D. Brown, On the geometry of O–H⋯O hydrogen bonds Acta Crystallographica Section A. ,vol. 32, pp. 24- 31 ,(1976) , 10.1107/S0567739476000041
Oscar Castillo, Antonio Luque, Pascual Román, Francesc Lloret, Miguel Julve, Syntheses, crystal structures, and magnetic properties of one-dimensional oxalato-bridged Co(II), Ni(II), and Cu(II) complexes with n-aminopyridine (n = 2-4) as terminal ligand. Inorganic Chemistry. ,vol. 40, pp. 5526- 5535 ,(2001) , 10.1021/IC0103401
Catalina Ruiz-Pérez, Yolanda Rodríguez-Martín, Trinidad López, Francesc Lloret, Miguel Julve, Fernando S. Delgado, María Hernández-Molina, Joaquín Sanchiz, Synthesis, crystal structure and magnetic properties of two-dimensional malonato-bridged cobalt(II) and nickel(II) compounds CrystEngComm. ,vol. 6, pp. 106- 111 ,(2004) , 10.1039/B403640A