Chemical reactivities of the cation and anion of M@C82 (M = Y, La, and Ce).
作者： Yutaka Maeda , Jun Miyashita , Tadashi Hasegawa , Takatsugu Wakahara , Takahiro Tsuchiya
DOI: 10.1021/JA043986B
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摘要: The chemical reduction and oxidation of M@C82 (M = Y, La, Ce) afford the corresponding anion cation, respectively, which show unique interesting reactivities. It is found that successful reversible gain or loss electrons by ionization useful for controlling stability reactivity toward both nucleophiles electrophiles.
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