Polyoxoanions in Catalysis: From Record Catalytic Lifetime Nanocluster Catalysis to Record Catalytic Lifetime Catechol Dioxygenase Catalysis

摘要: Following an introductory overview of the 8 newer classes polyoxoanion-based catalysts in last 20 years, as well 3 subclasses investigated by Finke Group, highlights are presented research which has led to two catalysts: polyoxonion-stabilized transition metal nanocluster “soluble heterogeneous catalysts” and precatalysts for catechol dioxygenase activity. In both cases, resultant show record catalytic lifetime high An introduction catalysis, including some key goals area, is also provided. The a recently reported, polyoxoanion •FeII-based stiochiometric extradiol then presented. Key findings from polyoxoanion-derived next, exhibit activity lifetime. A summary, emphasizing 4 components have polyoxoanion-stabilized catalysts,