Viscosity and surface tension of binary systems of N,N -dimethylformamide with alkan-1-ols at different temperatures
作者： Abubaker A. Mohammad , Khaled H.A.E. Alkhaldi , Mohammad S. AlTuwaim , Adel S. Al-Jimaz
DOI: 10.1016/J.JCT.2012.06.023
关键词:
摘要: Abstract Viscosity η and surface tension σ were measured for binary mixtures of N,N -dimethylformamide DMF with pentan-1-ol, hexan-1-ol, heptan-1-ol at T = (298.15, 303.15, 308.15, 313.15) K atmospheric pressure over the entire mole fraction range. Deviations in viscosity Δ Δσ calculated using experimental results. Moreover, values excess Gibbs free energy activation G ∗E , enthalpy H entropy S these determined. measurements systems correlated Grunberg Nissan, three-body four-body McAllister expressions. deviation, deviation functions fitted to method Redlich–Kister (R–K) polynomial estimate coefficients standard deviations. The effects chain length alkan-1-ols temperature on thermodynamic properties studied.
sci-hub.se 参考文章(28)
Yizhak Marcus, The properties of solvents ,(1998)
Shantilal Oswal, Manapragada V. Rathnam, Viscosity data of binary mixtures: ethyl acetate + cyclohexane, + benzene, + toluene, + ethylbenzene + carbon tetrachloride, and + chloroform at 303.15 K Canadian Journal of Chemistry. ,vol. 62, pp. 2851- 2853 ,(1984) , 10.1139/V84-482
R. J. Fort, W. R. Moore, Viscosities of binary liquid mixtures Transactions of The Faraday Society. ,vol. 62, pp. 1112- 1119 ,(1966) , 10.1039/TF9666201112
Vidya A. Aminabhavi, Tejraj M. Aminabhavi, Ramachandra H. Balundgi, Evaluation of excess parameters from densities and viscosities of binary mixtures of ethanol with anisole, N,N-dimethylformamide, carbon tetrachloride, and acetophenone from 298.15 to 313.15 K Industrial & Engineering Chemistry Research. ,vol. 29, pp. 2106- 2111 ,(1990) , 10.1021/IE00106A020
Otto Redlich, A. T. Kister, Algebraic Representation of Thermodynamic Properties and the Classification of Solutions Industrial & Engineering Chemistry. ,vol. 40, pp. 345- 348 ,(1948) , 10.1021/IE50458A036
Mohammad S. AlTuwaim, Khaled H.A.E. Alkhaldi, Adel S. Al-Jimaz, Abubaker A. Mohammad, Comparative study of physico-chemical properties of binary mixtures of N,N-dimethylformamide with 1-alkanols at different temperatures The Journal of Chemical Thermodynamics. ,vol. 48, pp. 39- 47 ,(2012) , 10.1016/J.JCT.2011.12.002
Zhengjun Shan, Abdul-Fattah A. Asfour, Viscosities and Densities of Nine Binary 1-Alkanol Systems at 293.15 K and 298.15 K Journal of Chemical & Engineering Data. ,vol. 44, pp. 118- 123 ,(1999) , 10.1021/JE980177X
Anil Kumar, Surface tension, viscosity, vapor pressure, density, and sound velocity for a system miscible continuously from a pure fused electrolyte to a nonaqueous liquid with a low dielectric constant : anisole with tetra-n-butylammonium picrate Journal of the American Chemical Society. ,vol. 115, pp. 9243- 9248 ,(1993) , 10.1021/JA00073A045
P. Venkatesu, Thermophysical contribution of N,N-dimethylformamide in the molecular interactions with other solvents Fluid Phase Equilibria. ,vol. 298, pp. 173- 191 ,(2010) , 10.1016/J.FLUID.2010.07.010
Yang-Yi Yang, Jian-Hong Deng, Hai-Ling Yang, Xiu-Huan Zheng, Guan-Quan Che, Zhong-Qi Huang, Densities, surface tensions, and derived surface thermodynamics properties of (trimethylbenzene + propyl acetate, or butyl acetate) from T = 298.15 K to 313.15 K The Journal of Chemical Thermodynamics. ,vol. 39, pp. 438- 448 ,(2007) , 10.1016/J.JCT.2006.07.025