Analysis of Surfactants in Environmental Samples by Chromatographic Techniques

作者: Juan M. , Eduardo Gonzalez-Mazo , Pablo A.

DOI: 10.5772/48475

关键词:

摘要: Synthetic surfactants are among the most produced and used organic compounds worldwide. They a wide range of chemicals characterized by their amphiphilic nature. Thus, molecules consist an hydrophilic / polar head group (either charged or uncharged) hydrophobic nonpolar hydrocarbon tail. As consequence, show solubility in liquids, ability to form micelles, adsorption phase boundaries reduction surface tension water. economically important due specific properties that allow using them as washing, wetting, emulsifying dispersing agents. Therefore, mainly formulation detergents, personal care products, paints, textiles, pesticide formulations, pharmaceutical, many other products [1, 2]. Many different types these have been synthesized, although they can be classified into three main groups according charge: (1) anionics, (2) non-ionics, (3) cationics (Figure 1); first second accounting for highest production volumes. European Committee Organic Surfactants Intermediates (CESIO) reported 1200 ktons anionic 1400 non-ionic Europe 2010, which represents 90% total surfactants.

参考文章(138)
Noelia Luque, Francisco Merino, Soledad Rubio, Dolores Pérez-Bendito, Stability of benzalkonium surfactants on hemimicelle-based solid-phase extraction cartridges Journal of Chromatography A. ,vol. 1094, pp. 17- 23 ,(2005) , 10.1016/J.CHROMA.2005.07.102
Migaku Kawaguchi, Norihiro Sakui, Noriya Okanouchi, Rie Ito, Koichi Saito, Hiroyuki Nakazawa, Stir bar sorptive extraction and trace analysis of alkylphenols in water samples by thermal desorption with in tube silylation and gas chromatography–mass spectrometry Journal of Chromatography A. ,vol. 1062, pp. 23- 29 ,(2005) , 10.1016/J.CHROMA.2004.11.033
Niels Jonkers, Remi W. P. M. Laane, Pim de Voogt, Fate of nonylphenol ethoxylates and their metabolites in two Dutch estuaries: evidence of biodegradation in the field. Environmental Science & Technology. ,vol. 37, pp. 321- 327 ,(2003) , 10.1021/ES020121U
Wang-Hsien Ding, Shin-Haw Tzing, Jun-Hui Lo, Occurrence and concentrations of aromatic surfactants and their degradation products in river waters of Taiwan Chemosphere. ,vol. 38, pp. 2597- 2606 ,(1999) , 10.1016/S0045-6535(98)00467-6
Tomohiko Isobe, Hideshige Takada, Determination of degradation products of alkylphenol polyethoxylates in municipal wastewaters and rivers in Tokyo, Japan Environmental Toxicology and Chemistry. ,vol. 23, pp. 599- 605 ,(2004) , 10.1897/03-263
Maria Concetta Bruzzoniti, Rosa Maria De Carlo, Corrado Sarzanini, Determination of sulfonic acids and alkylsulfates by ion chromatography in water. Talanta. ,vol. 75, pp. 734- 739 ,(2008) , 10.1016/J.TALANTA.2007.12.026