Signal Amplification of a “Turn-On” Sensor: Harvesting the Light Captured by a Conjugated Polymer

作者: D. Tyler McQuade , Ashleigh H. Hegedus , Timothy M. Swager

DOI: 10.1021/JA003255L

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摘要: The system is designed so that pH alters the absorption cross-section, energy migration efficiency, and emission efficiency ofthe fluoresceinamine (FA) dye appended off of polymer 2.Inthis case, acts as a shunt, withdrawing from theconjugated polymer. At high pH, FA highly absorptive andhighly fluorescent, while at low dye’s extinction coef-ficient decreases fluorescence lost. In our case,electrostatic binding anionic 2 onto cationic surfaceformed by depositing 1 directly glass substrate provides afacile method for placing in close proximity tothe conjugated

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