Glycerol dialkyl glycerol tetraethers (GDGT) distributions from soil to cave: refining the speleothem paleothermometer

作者: Andy Baker , Alison J. Blyth , Catherine N. Jex , James A. Mcdonald , Martijn Woltering

DOI: 10.1016/J.ORGGEOCHEM.2019.06.011

关键词:

摘要: Abstract The glycerol dialkyl tetraether (GDGT) paleothermometer has potential application as a speleothem paleoclimate proxy. However, the sources of GDGTs found in speleothems are poorly understood, with multiple from soil to surface. Here we analysed soils, leachates, in-cave surfaces and cave drip waters at two Australian montane caves. We observed significantly different GDGT distributions between significant spatial differences distributions. Comparison published modern karst groundwater datasets Australia, Europe China shows that those all sources. hypothesise have calcifying, alkaline, oxic, wet, carbon-available, environment supports microbial community is other possible propose presence related anoxic or methanogenic conditions, water on surfaces, can be used identify these confirm TEX86 based paleothermometers robust paleothermometers, whose calibration further refined through improved understanding measurement temperatures.

参考文章(35)
Jonathan Dredge, Aerosol contributions to speleothem geochemistry AGUFM. ,vol. 2011, ,(2014)
Gabriel C. Rau, Mark O. Cuthbert, Martin S. Andersen, Andy Baker, Helen Rutlidge, Monika Markowska, Hamid Roshan, Christopher E. Marjo, Peter W. Graham, R. Ian Acworth, Controls on cave drip water temperature and implications for speleothem-based paleoclimate reconstructions Quaternary Science Reviews. ,vol. 127, pp. 19- 36 ,(2015) , 10.1016/J.QUASCIREV.2015.03.026
Lindsay Powers, Josef P. Werne, Andrea J. Vanderwoude, Jaap S. Sinninghe Damsté, Ellen C. Hopmans, Stefan Schouten, Applicability and calibration of the TEX86 paleothermometer in lakes. Organic Geochemistry. ,vol. 41, pp. 404- 413 ,(2010) , 10.1016/J.ORGGEOCHEM.2009.11.009
Alison J. Blyth, Catherine N. Jex, Andy Baker, Stuart J. Khan, Stefan Schouten, Contrasting distributions of glycerol dialkyl glycerol tetraethers (GDGTs) in speleothems and associated soils Organic Geochemistry. ,vol. 69, pp. 1- 10 ,(2014) , 10.1016/J.ORGGEOCHEM.2014.01.013
Albert Goede, Frank McDermott, Chris Hawkesworth, John Webb, Brian Finlayson, Evidence of Younger Dryas and Neoglacial cooling in a Late Quaternary palaeotemperature record from a speleothem in eastern Victoria, Australia Journal of Quaternary Science. ,vol. 11, pp. 1- 7 ,(1996) , 10.1002/(SICI)1099-1417(199601/02)11:1<1::AID-JQS219>3.0.CO;2-2
Peter M. Wynn, Ian J. Fairchild, Andy Baker, James U.L. Baldini, Frank McDermott, Isotopic archives of sulphate in speleothems Geochimica et Cosmochimica Acta. ,vol. 72, pp. 2465- 2477 ,(2008) , 10.1016/J.GCA.2008.03.002
Stefan Schouten, Ellen C. Hopmans, Jaap S. Sinninghe Damsté, The organic geochemistry of glycerol dialkyl glycerol tetraether lipids: A review Organic Geochemistry. ,vol. 54, pp. 19- 61 ,(2013) , 10.1016/J.ORGGEOCHEM.2012.09.006
Monika Markowska, Andy Baker, Pauline C. Treble, Martin S. Andersen, Stuart Hankin, Catherine N. Jex, Carol V. Tadros, Regina Roach, Unsaturated zone hydrology and cave drip discharge water response: Implications for speleothem paleoclimate record variability Journal of Hydrology. ,vol. 529, pp. 662- 675 ,(2015) , 10.1016/J.JHYDROL.2014.12.044
Huan Yang, Weihua Ding, Chuanlun L. Zhang, Xia Wu, Xiufeng Ma, Gangqiang He, Junhua Huang, Shucheng Xie, Occurrence of tetraether lipids in stalagmites: Implications for sources and GDGT-based proxies Organic Geochemistry. ,vol. 42, pp. 108- 115 ,(2011) , 10.1016/J.ORGGEOCHEM.2010.11.006
Johan W.H. Weijers, Stefan Schouten, Jurgen C. van den Donker, Ellen C. Hopmans, Jaap S. Sinninghe Damsté, Environmental controls on bacterial tetraether membrane lipid distribution in soils Geochimica et Cosmochimica Acta. ,vol. 71, pp. 703- 713 ,(2007) , 10.1016/J.GCA.2006.10.003