Effects of oxide additions on electrochemical hydriding and dehydriding behavior of Mg2Ni-type hydrogen storage alloy electrode in 6 M KOH solution

作者: N. Cui , J.L. Luo

DOI: 10.1016/S0013-4686(98)00235-7

关键词:

摘要: Effects of metal oxide additions on the electrochemical hydriding and dehydriding behavior Mg2Ni-type hydrogen storage alloy in 6 M KOH aqueous solution were investigated. The electrode characteristics mechanically alloyed composites Mg1.9Y0.1Ni0.9Al0.1–5 wt% MO (MO=Ag2O, Fe2O3, MoO3, RuO2 V2O5) examined such as discharge capacity, high-rate dischargability cycle life. capacity greatly increased by modification with additions, but life decreased. performances characterized using both dc polarization ac impedance analysis techniques. diffusivity alloys was estimated an method.

参考文章(18)
E. Wicke, H. Brodowsky, H. Züchner, Hydrogen in palladium and palladium alloys hm2. ,vol. 29, pp. 73- 155 ,(1978) , 10.1007/3-540-08883-0_19
B. V. Ratnakumar, C. Witham, R. C. Bowman, A. Hightower, B. Fultz, Electrochemical Studies on LaNi(sub 5-x)Sn(sub x) Metal Hydride Alloys Journal of The Electrochemical Society. ,vol. 143, pp. 2578- 2584 ,(1996) , 10.1149/1.1837050
Chiaki Iwakura, Yukio Fukumoto, Masao Matsuoka, Tatsuoki Kohno, Katsuhide Shinmou, Electrochemical characterization of hydrogen storage alloys modified with metal oxides Journal of Alloys and Compounds. ,vol. 192, pp. 152- 154 ,(1993) , 10.1016/0925-8388(93)90215-9
Mark W. Verbrugge, Brian J. Koch, Modeling Lithium Intercalation of Single‐Fiber Carbon Microelectrodes Journal of The Electrochemical Society. ,vol. 143, pp. 600- 608 ,(1996) , 10.1149/1.1836486
Masao Matsuoka, Masayuki Terashima, Chiaka Iwakura, Effect of alloy composition on charge and discharge characteristics of the negative electrode for nickel—hydrogen batteries Electrochimica Acta. ,vol. 38, pp. 1087- 1092 ,(1993) , 10.1016/0013-4686(93)80217-N
M. Khrussanova, M. Terzieva, P. Peshev, E.Yu. Ivanov, On the hydriding and dehydriding kinetics of magnesium with a titanium dioxide admixture Materials Research Bulletin. ,vol. 22, pp. 405- 412 ,(1987) , 10.1016/0025-5408(87)90059-6
Nobuhiro Kuriyama, Tetsuo Sakai, Hiroshi Miyamura, Itsuki Uehara, Hiroshi Ishikawa, Toshikatsu Iwasaki, Electrochemical impedance and deterioration behavior of metal hydride electrodes Journal of Alloys and Compounds. ,vol. 202, pp. 183- 197 ,(1993) , 10.1016/0925-8388(93)90538-X
N Cui, B Luan, H Ks Liu, HJ Zhao, SX Dou, None, Characteristics of magnesium-based hydrogen-storage alloy electrodes Journal of Power Sources. ,vol. 55, pp. 263- 267 ,(1995) , 10.1016/0378-7753(95)02195-M