Polyiodination on benzene at room temperature a regioselective synthesis of derivatives.
作者： José Barluenga , José M. González , Miguel A. García-Martín , Pedro J. Campos
DOI: 10.1016/S0040-4039(00)79256-2
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摘要: Abstract Reaction of IPy2BF4 with benzene and CF3SO3H in CH2Cl2 gives regioselectively polyiodinated compounds at room temperature, providing a definitely easy synthetic entry to those rarely accessible derivatives.
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sci-hub.se 参考文章(13)
Bruce C. Berris, George H. Hovakeemian, Yee Hing Lai, Helene Mestdagh, K. Peter C. Vollhardt, A new approach to the construction of biphenylenes by the cobalt-catalyzed cocyclization of o-diethynylbenzenes with alkynes. Application to an iterative approach to [3]phenylene, the first member of a novel class of benzocyclobutadienoid hydrocarbons Journal of the American Chemical Society. ,vol. 107, pp. 5670- 5687 ,(1985) , 10.1021/JA00306A013
Guy Félix, Jacques Dunoguès, Francoise Pisciotti, Raymond Calas, Regiospecific Synthesis of Mono‐and Polyiodo Derivatives of Benzene Angewandte Chemie. ,vol. 16, pp. 488- 489 ,(1977) , 10.1002/ANIE.197704881
Daniell Lewis Mattern, Direct Aromatic Periodination Journal of Organic Chemistry. ,vol. 49, pp. 3051- 3053 ,(1984) , 10.1021/JO00191A003
J. C. Martin, L. J. Schaad, Sigma-delocalized aromatic species formed from cyclic arrays of hypervalent main-group element species Pure and Applied Chemistry. ,vol. 62, pp. 547- 550 ,(1990) , 10.1351/PAC199062030547
Thomas X. Neenan, George M. Whitesides, Synthesis of high carbon materials from acetylenic precursors. Preparation of aromatic monomers bearing multiple ethynyl groups Journal of Organic Chemistry. ,vol. 53, pp. 2489- 2496 ,(1988) , 10.1021/JO00246A018
Klaus Praefcke, Bernd Kohne, Dirk Singer, Hexaalkynyltriphenylene: A New Type of Nematic‐Discotic Hydrocarbon Angewandte Chemie. ,vol. 29, pp. 177- 179 ,(1990) , 10.1002/ANIE.199001771
James R. Green, Joachim Mittendorf, Debra L. Mohler, K. Peter C. Vollhardt, Roland Boese, The First Hexabutadiynylbenzenes: Synthesis and Structures Angewandte Chemie. ,vol. 31, pp. 1643- 1645 ,(1992) , 10.1002/ANIE.199216431
GB Deacon, GJ Farquharson, Permercurated arenes. III. Syntheses of periodoarenes and perchloroarenes by Iodo- and Chloro-demercuration of some permercurated arenes Australian Journal of Chemistry. ,vol. 30, pp. 1701- 1713 ,(1977) , 10.1071/CH9771701
Daniell Lewis Mattern, Xinhua Chen, None, Direct polyiodination of benzenesulfonic acid Journal of Organic Chemistry. ,vol. 56, pp. 5903- 5907 ,(1991) , 10.1021/JO00020A036
Daniell Lewis Mattern, None, Periodination of benzene with periodate/iodide Journal of Organic Chemistry. ,vol. 48, pp. 4772- 4773 ,(1983) , 10.1021/JO00172A063