Synthesis, crystal structure and gas uptake properties of a urea-functionalized rht-type metal–organic framework
作者： Qiu-Yan Li , Ying Quan , Wei Wei , Jian Li , Han Lu
DOI: 10.1016/J.POLY.2015.06.001
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摘要: Abstract A hexatopic C3-symmetrical 5,5′,5″-(((benzene-1,3,5-triyltris(azanediyl))tris(carbonyl))tris-(azanediyl))triisophthalic acid (H6-1) linker containing tri-urea groups has been designed and synthesized through the reaction between 1,3,5-benzenetriisocyanate aniline, which was employed to construct a new copper(II) metal–organic framework (MOF Cu-TUH) under solvothermal with Cu(NO3)2 in N,N-dimethylformamide. As expected, single crystal X-ray diffraction study reveals that MOF Cu-TUH is composed of 3D packing nanosized cuboctahedral, truncated tetrahedral, octahedral cages (3,24)-connected rht-topology. Furthermore, preliminary gas uptake investigations activated were conducted evaluate its application area storage purifications.
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