Preparation and properties of ZnBr(CF3)·2L — a convenient route for the preparation of CF3I
作者： Dieter Naumann , Wieland Tyrra , Birgit Kock , Werner Rudolph , Bernd Wilkes
DOI: 10.1016/0022-1139(93)02937-A
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摘要: Abstract ZnBr(CF 3 )·2L (L=DMF, CH CN) can easily be prepared by the reactions of CBrF with elemental zinc in better than 60% yield. The reaction )·2DMF iodine monochloride DMF solution yields pure CF I 70% yield via an ecologically less damaging pathway decarboxylation route using silver or mercury trifluoroacetates.
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