Formation of silicon nitride from silica

作者: T. S. Bartnitskaya , P. P. Pikuza , I. I. Timofeeva , E. S. Lugovskaya , T. Ya. Kosolapova

DOI: 10.1007/BF00805645

关键词:

摘要: The formation of Si3N4, during the carbothermic reduction SiO2 in presence small Fe additions combined with nitridation is a complex process involving several solid-solid, gas-solid, gas-liquid-solid, and gas-gas reaction stages. catalytic action iron manifests itself an intermediate compound — carbosilicide. product FeSixCy isα-Si3N4, that silicon, β-Si3N4.

参考文章(11)
Ludwig Weiss, Theodor Engelhardt, Über die Stickstoffverbindungen des Siliciums Zeitschrift für anorganische und allgemeine Chemie. ,vol. 65, pp. 38- 104 ,(1910) , 10.1002/ZAAC.19090650107
S. A. Badrak, T. S. Bartnitskaya, I. M. Baryshevskaya, T. Ya. Kosolapova, P. P. Pikuza, B. G. Trusov, V. P. Turov, Thermodynamic calculations for the assessment of possible ways of formation of silicon nitride Powder Metallurgy and Metal Ceramics. ,vol. 20, pp. 643- 647 ,(1981) , 10.1007/BF00801575
M. Mitomo, Effect of Fe and Al additions on nitridation of silicon Journal of Materials Science. ,vol. 12, pp. 273- 276 ,(1977) , 10.1007/BF00566267
PATRICK D. MILLER, J. G. LEE, IVAN B. CUTLER, The Reduction of Silica with Carbon and Silicon Carbide Journal of the American Ceramic Society. ,vol. 62, pp. 147- 149 ,(1979) , 10.1111/J.1151-2916.1979.TB19041.X
S. M. Boyer, A. J. Moulson, A mechanism for the nitridation of Fe-contaminated silicon Journal of Materials Science. ,vol. 13, pp. 1637- 1646 ,(1978) , 10.1007/BF00548727
N. N. Minenko, T. N. Nazarchuk, Determination of nitrogen in nitrides undecomposable by acids Powder Metallurgy and Metal Ceramics. ,vol. 4, pp. 477- 478 ,(1965) , 10.1007/BF00773970
K. Komeya, H. Inoue, Synthesis of the ? form of silicon nitride from silica Journal of Materials Science. ,vol. 10, pp. 1243- 1246 ,(1975) , 10.1007/BF00541410
SHI-CHANG ZHANG, W. ROGER CANNON, Preparation of Silicon Nitride from Silica Journal of the American Ceramic Society. ,vol. 67, pp. 691- 695 ,(1984) , 10.1111/J.1151-2916.1984.TB19684.X
SIN-SHONG LIN, Comparative Studies of Metal Additives on the Nitridation of Silicon Journal of the American Ceramic Society. ,vol. 60, pp. 78- 81 ,(1977) , 10.1111/J.1151-2916.1977.TB16101.X
J. G. Lee, Ivan B. Cutler, Reactions in the SiO2-C-N2 System Springer Netherlands. pp. 175- 181 ,(1977) , 10.1007/978-94-010-1298-0_12