Comment on "Accurate experimental values for the free energies of hydration of H+, OH-, and H3O+".
作者： Donald M. Camaioni , Christine A. Schwerdtfeger
DOI: 10.1021/JP054088K
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摘要: In the subject paper, Plascak and Shields claim to have derived accurate experimental values for hydration free energies of H+, OH?, H3O+. The purpose this comment is alert community that, in fact, their are less than they meant replace. what follows we show errors PS made and, by example, give practical advice on how ensure correct assignment standard states reactions with water as a reactant or product gas solution phases.
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