Orthogonal Smectic Layers Favour Nucleation through Diffusioncontrolled Transformations: A Systematic Crystallization Kinetics Study

摘要: Systematic investigations of the crystallization kinetics two representative compounds p-phenylbenzylidene-p'-alkylanilines are performed, using differential scanning calorimetry, to study influence kinetophase (occurs prior crystal phase) on nucleation process. The dimensionality growth and related process discussed in terms Avrami parameters n b. trend magnitude exponent supports occurrence temperature-dependent transformations orthorhombic molecular array.