Kinetic separation of hexane isomers by fixed-bed adsorption with a microporous metal-organic framework.

作者： Patrick S. Bárcia , Fatima Zapata , José A. C. Silva , Alírio E. Rodrigues , Banglin Chen

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摘要: A three-dimensional microporous metal−organic framework Zn(BDC)(Dabco)0.5 (BDC = 1,4-benzenedicarboxylate, Dabco 1,4-diazabicyclo [2,2,2]octane), having two types of intersecting pores to encapsulate linear hexane and block branched hexanes, thus exhibiting highly selective sorption with respect n-hexane, has been successfully applied the kinetic separation isomers by fixed-bed adsorption.