Reductive Splitting of Cellulose in the Ionic Liquid 1‐Butyl‐3‐Methylimidazolium Chloride
作者： Igor A Ignatyev , Charlie Van Doorslaer , Pascal GN Mertens , Koen Binnemans , Dirk E De Vos
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摘要: The depolymerization of cellulose is carried out in the ionic liquid 1-butyl-3-methylimidazolium chloride presence hydrogen gas. First, ketal 1,1-diethoxycyclohexane and cellobiose were used as model substrates. For itself, combination a heterogeneous metal catalyst homogeneous ruthenium proved effective. One possible roles compound to enhance transfer metallic surface. fully converted under relatively mild conditions, with sorbitol dominant product 51–74 % yield.
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