Mixed anionic-nonionic micelle catalysed oxidation of aliphatic alcohol in aqueous medium
作者： Animesh Acharjee , Atanu Rakshit , Suman Chowdhury , Md. Ansar Ali , Bula Singh
DOI: 10.1016/J.MOLLIQ.2020.112655
关键词:
摘要: Abstract Oxidation of isoamyl alcohol was carried out under pseudo 1st order reaction condition in aqueous medium by chromic acid. In addition to single micelle, mixed anionic-nonionic micelle (SDS-TX 100) found be effective catalyst. Promoters presence catalyst showed almost million fold rate acceleration. The product confirmed IR and NMR study. UV analysis were establish the formation micelle. Formation active oxidant fluorescence measurement. Interactions between surfactant substrate analysed spectra. SDS catalysed Bpy promoted combination with promoter show higher oxidation. For path observed constants follow kobs (SDS) > kobs (TX (Phen) > kobs (Bpy) > kobs (PA) for reactions. while TX 100 found.
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