Preparation and Oxygen Permeation of U-Shaped Perovskite Hollow-Fiber Membranes

作者: Yanying Wei , Hongfei Liu , Jian Xue , Zhong Li , Haihui Wang

DOI: 10.1002/AIC.12321

关键词:

摘要: The oxygen permeation of dense U-shaped perovskite hollow-fiber membranes based on Ba 0.5 Sr Co 0.8 Fe 0.2 O 3―δ prepared by a phase inversion spinning process is reported. hollow fibers with totally wall were obtained the outer diameter 1.147 mm and inner 0.691 mm. dependences air flow rate shell side, helium core partial pressures, operating temperatures experimentally investigated. According to Wagner theory, it follows that transport through membrane controlled both surface reaction bulk diffusion at temperature ranges 750―950°C. High flux 3.0 ml/(min cm 2 ) was kept for about 250 h 950°C under conditions feed 150 mllmin 50 mllmin.

参考文章(47)
Haihui Wang, You Cong, Weishen Yang, High selectivity of oxidative dehydrogenation of ethane to ethylene in an oxygen permeable membrane reactor. Chemical Communications. pp. 1468- 1469 ,(2002) , 10.1039/B203168J
Xiaoyao Tan, Yutie Liu, K. Li, Preparation of LSCF Ceramic Hollow-Fiber Membranes for Oxygen Production by a Phase-Inversion/Sintering Technique Industrial & Engineering Chemistry Research. ,vol. 44, pp. 61- 66 ,(2005) , 10.1021/IE040179C
F.T. Akin, Jerry Y.S. Lin, Oxygen permeation through oxygen ionic or mixed-conducting ceramic membranes with chemical reactions Journal of Membrane Science. ,vol. 231, pp. 133- 146 ,(2004) , 10.1016/J.MEMSCI.2003.11.012
Alan Thursfield, Ian S. Metcalfe, Air separation using a catalytically modified mixed conducting ceramic hollow fibre membrane module Journal of Membrane Science. ,vol. 288, pp. 175- 187 ,(2007) , 10.1016/J.MEMSCI.2006.11.015
Xiaoyao Tan, Zhigang Wang, Hua Liu, Shaomin Liu, None, Enhancement of oxygen permeation through La0.6Sr0.4Co0.2Fe0.8O3−δ hollow fibre membranes by surface modifications Journal of Membrane Science. ,vol. 324, pp. 128- 135 ,(2008) , 10.1016/J.MEMSCI.2008.07.008
Shaomin Liu, George R. Gavalas, Preparation of Oxygen Ion Conducting Ceramic Hollow-Fiber Membranes Industrial & Engineering Chemistry Research. ,vol. 44, pp. 7633- 7637 ,(2005) , 10.1021/IE040279I
Xiaoyao Tan, Yutie Liu, K. Li, Mixed conducting ceramic hollow‐fiber membranes for air separation Aiche Journal. ,vol. 51, pp. 1991- 2000 ,(2005) , 10.1002/AIC.10475
M. Trunec, Fabrication of zirconia- and ceria-based thin-wall tubes by thermoplastic extrusion Journal of The European Ceramic Society. ,vol. 24, pp. 645- 651 ,(2004) , 10.1016/S0955-2219(03)00258-9
T SCHIESTEL, M KILGUS, S PETER, K CASPARY, H WANG, J CARO, Hollow fibre perovskite membranes for oxygen separation Journal of Membrane Science. ,vol. 258, pp. 1- 4 ,(2005) , 10.1016/J.MEMSCI.2005.03.035