CESIUM FLUORIDE PROMOTED HALOGENATION OF CYANOGEN BY CHLORINE AND BROMINE AND SELECTED REACTIONS OF PRODUCTS

作者: Qui Chi. Mir , Darryl D. DesMarteau

DOI: 10.1021/IC00003A036

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摘要: The reaction of cyanogen with Cl 2 and Br in the presence CsF gives rise to a series compounds, NCCF=NX (Cl, Br), XN=CF-CF=NX (Br), NCCF NX (Cl). Subsequent reactions NCl MF/Br (M=Cs, K, Na) give X'N=CFCF=NX, XN=CFCF NXX', NXX'(X, X'=Cl, involving oxidation exchange by Br. Photolysis NXX' respective azine diazene

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