Conformation Improving Construction of Ag3L2 Metallocages and Their Selective Encapsulation
作者： Guangxun Lyu , Qihui Chen , Feilong Jiang , Daqiang Yuan , Hui Xue
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摘要: A novel tripodal ligand L that only has a syn conformer been designed and synthesized. Different Ag3L2 metallocages can be effectively assembled from such concave ligands different Ag(I) salts. ESI-MS research indicates metallocage encapsulate anions selectively, in which the encapsulation capacity is as follows: NO3– > ClO4– SO42–; moreover, selective of mixture observed.
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scilit.net参考文章(51)
Qihui Chen, Lian Chen, Feilong Jiang, Maochun Hong, Controllable Coordination Self-Assembly Based on Flexible Tripodal Ligands: From Finite Metallocages to Infinite Polycatenanes Step by Step. Chemical Record. ,vol. 15, pp. 711- 727 ,(2015) , 10.1002/TCR.201402095
Cheng-Yong Su, Yue-Peng Cai, Chun-Long Chen, Falk Lissner, Bei-Sheng Kang, Wolfgang Kaim, Self-assembly of trigonal-prismatic metallocages encapsulating BF4- or CuI32- as anionic guests: structures and mechanism of formation. Angewandte Chemie. ,vol. 41, pp. 3371- 3375 ,(2002) , 10.1002/1521-3773(20020916)41:18<3371::AID-ANIE3371>3.0.CO;2-4
James J. Henkelis, Tanya K. Ronson, Lindsay P. Harding, Michaele J. Hardie, M3L2 metallo-cryptophanes: [2]catenane and simple cages Chemical Communications. ,vol. 47, pp. 6560- 6562 ,(2011) , 10.1039/C1CC10806A
Harshita Kumari, Ping Jin, Simon J. Teat, Charles L. Barnes, Scott J. Dalgarno, Jerry L. Atwood, Strong cation···π interactions promote the capture of metal ions within metal-seamed nanocapsule. Journal of the American Chemical Society. ,vol. 136, pp. 17002- 17005 ,(2014) , 10.1021/JA5107354
Timothy R. Cook, Peter J. Stang, Recent Developments in the Preparation and Chemistry of Metallacycles and Metallacages via Coordination Chemical Reviews. ,vol. 115, pp. 7001- 7045 ,(2015) , 10.1021/CR5005666
Sandip Mukherjee, Partha Sarathi Mukherjee, Template-free multicomponent coordination-driven self-assembly of Pd(ii)/Pt(ii) molecular cages Chem. Commun.. ,vol. 50, pp. 2239- 2248 ,(2014) , 10.1039/C3CC49192G
Oleg Chepelin, Jakub Ujma, Xiaohua Wu, Alexandra M. Z. Slawin, Mateusz B. Pitak, Simon J. Coles, Julien Michel, Anita C. Jones, Perdita E. Barran, Paul J. Lusby, Luminescent, Enantiopure, Phenylatopyridine Iridium-Based Coordination Capsules Journal of the American Chemical Society. ,vol. 134, pp. 19334- 19337 ,(2012) , 10.1021/JA309031H
Chao Wang, Xin-Qi Hao, Ming Wang, Cunlan Guo, Bingqian Xu, Eric N. Tan, Yan-Yan Zhang, Yihua Yu, Zhong-Yu Li, Hai-Bo Yang, Mao-Ping Song, Xiaopeng Li, Self-assembly of giant supramolecular cubes with terpyridine ligands as vertices and metals on edges Chemical Science. ,vol. 5, pp. 1221- 1226 ,(2014) , 10.1039/C3SC52965G
Salvatore Zarra, Daniel M. Wood, Derrick A. Roberts, Jonathan R. Nitschke, Molecular containers in complex chemical systems Chemical Society Reviews. ,vol. 44, pp. 419- 432 ,(2015) , 10.1039/C4CS00165F
Xuzhou Yan, Timothy R. Cook, Pi Wang, Feihe Huang, Peter J. Stang, Highly emissive platinum( II ) metallacages Nature Chemistry. ,vol. 7, pp. 342- 348 ,(2015) , 10.1038/NCHEM.2201