The borohydride ion (BH4−) in a face-centred cubic alkali-halide lattice
作者： J.A.A. Ketelaar , C.J.H. Schutte
DOI: 10.1016/0371-1951(61)80046-5
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摘要: The crystal field which surrounds a polyatomic ion in lattice acts as perturbation on the vibrational levels and influences them to large extent. It depends upon symmetry of surrounding whether degenerate may be split infra-red inactive vibrations become active. influence (face-centred) cubic-crystal borohydride ion, imbedded alkali-halides, is discussed. local group BH4− found Td solid solutions studied.
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