Supported Single Atoms as New Class of Catalysts for Electrochemical Reduction of Carbon Dioxide

作者: Yi Cheng , Shize Yang , San Ping Jiang , Shuangyin Wang

DOI: 10.1002/SMTD.201800440

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摘要: Carbon dioxide (CO2) emitted from excess consumption of fossil fuels leads to the rise of CO2 concentrations in the atmosphere. One of the most attractive solutions to cut CO2 emission is the electrochemical reduction of CO2 to produce fuels and build a low carbon emission economy. However, the electrochemical CO2 reduction reaction (CO2RR) is a great challenge due to the activation of the highly stable, linear CO2 molecules, and the process involves proton‐coupled multi‐electron transfer with a high energy barrier. Thus, it …

参考文章(147)
Bing Ni, Xun Wang, Face the Edges: Catalytic Active Sites of Nanomaterials. Advanced Science. ,vol. 2, pp. 1500085- 1500085 ,(2015) , 10.1002/ADVS.201500085
Cyrille Costentin, Marc Robert, Jean-Michel Savéant, Arnaud Tatin, Efficient and selective molecular catalyst for the CO2-to-CO electrochemical conversion in water. Proceedings of the National Academy of Sciences of the United States of America. ,vol. 112, pp. 6882- 6886 ,(2015) , 10.1073/PNAS.1507063112
J. Monzó, Y. Malewski, R. Kortlever, F. J. Vidal-Iglesias, J. Solla-Gullón, M. T. M. Koper, P. Rodriguez, Enhanced electrocatalytic activity of Au@Cu core@shell nanoparticles towards CO2 reduction Journal of Materials Chemistry. ,vol. 3, pp. 23690- 23698 ,(2015) , 10.1039/C5TA06804E
Marc D. Porosoff, Binhang Yan, Jingguang G. Chen, Catalytic reduction of CO2 by H2 for synthesis of CO, methanol and hydrocarbons: challenges and opportunities Energy and Environmental Science. ,vol. 9, pp. 62- 73 ,(2016) , 10.1039/C5EE02657A
Yawei Li, Siew Hwa Chan, Qiang Sun, Heterogeneous catalytic conversion of CO2: a comprehensive theoretical review Nanoscale. ,vol. 7, pp. 8663- 8683 ,(2015) , 10.1039/C5NR00092K
Dunfeng Gao, Hu Zhou, Jing Wang, Shu Miao, Fan Yang, Guoxiong Wang, Jianguo Wang, Xinhe Bao, Size-dependent electrocatalytic reduction of CO2 over Pd nanoparticles. Journal of the American Chemical Society. ,vol. 137, pp. 4288- 4291 ,(2015) , 10.1021/JACS.5B00046
Jingjie Wu, Ram Manohar Yadav, Mingjie Liu, Pranav P. Sharma, Chandra Sekhar Tiwary, Lulu Ma, Xiaolong Zou, Xiao-Dong Zhou, Boris I. Yakobson, Jun Lou, Pulickel M. Ajayan, Achieving Highly Efficient, Selective, and Stable CO2 Reduction on Nitrogen-Doped Carbon Nanotubes. ACS Nano. ,vol. 9, pp. 5364- 5371 ,(2015) , 10.1021/ACSNANO.5B01079
Ming Gong, Wu Zhou, Mon-Che Tsai, Jigang Zhou, Mingyun Guan, Meng-Chang Lin, Bo Zhang, Yongfeng Hu, Di-Yan Wang, Jiang Yang, Stephen J. Pennycook, Bing-Joe Hwang, Hongjie Dai, Nanoscale nickel oxide/nickel heterostructures for active hydrogen evolution electrocatalysis Nature Communications. ,vol. 5, pp. 4695- ,(2014) , 10.1038/NCOMMS5695
Horace Herring, Energy efficiency—a critical view Energy. ,vol. 31, pp. 10- 20 ,(2006) , 10.1016/J.ENERGY.2004.04.055
Xiao-Feng Yang, Aiqin Wang, Botao Qiao, Jun Li, Jingyue Liu, Tao Zhang, Single-atom catalysts: a new frontier in heterogeneous catalysis. Accounts of Chemical Research. ,vol. 46, pp. 1740- 1748 ,(2013) , 10.1021/AR300361M